1597442-29-9Relevant academic research and scientific papers
Reductive generation of stable, five-membered N,N′-diamidocarbenes
Moerdyk, Jonathan P.,Bielawski, Christopher W.
, p. 4551 - 4553 (2014/05/06)
The synthesis of the first stable, five-membered N,N′-diamidocarbenes (DACs), including a differentially N-substituted derivative, was achieved via the reduction of a geminal dichloride precursor using potassium. Key differences between the reactivity of the five-membered DACs and their six-membered congeners were observed, including an ability to insert into electron-rich C-H bonds. the Partner Organisations 2014.
