159763-34-5Relevant academic research and scientific papers
Some mechanistic and synthetic aspects of the DABCO catalysed rearrangement of allylic esters
Mason, Paul H.,Emslie, Neville D.
, p. 12001 - 12008 (1994)
Experimental evidence shows that the DABCO catalysed rearrangement of allylic esters proceeds via a two path mechanism, rather than a single path, as has been previously proposed. The effectiveness of other catalysts as well as E:Z ratios for these DABCO catalysed reactions have also been determined.
A new route to substituted glutaric acid derivatives from allylic malonates
Mason,Emslie,Drewes
, p. 183 - 190 (2007/10/02)
A new, high yielding route to substituted glutaric acid derivatives via anester enolate Claisen rearrangement of allylic malonates is described.
