1599472-47-5

Basic information

• Product Name: C₁₄H₂₄
• CAS NO: 1599472-47-5
• Molecular Weight: 192.345
• Mol File: 1599472-47-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: C₁₄H₂₄(CAS DataBase Reference)
• NIST Chemistry Reference: C₁₄H₂₄(1599472-47-5)
• EPA Substance Registry System: C₁₄H₂₄(1599472-47-5)

Safety Data

• Hazardous Substances Data: 1599472-47-5(Hazardous Substances Data)

Upstream product

• 37881-09-7 1-acetyl-4-tert-butylcyclohex-1-ene 
• 1530-32-1 ethyltriphenylphosphonium bromide 

Relevant articles and documents

Chemoselective reactions of (E)-1,3-dienes: Cobalt-mediated isomerization to (z)-1,3-dienes and reactions with ethylene

In the asymmetric hydrovinylation (HV) of an E/Z-mixture of a prototypical 1,3-diene with (S,S)-(DIOP)CoCl2 or (S,S)-(BDPP)CoCl2 catalyst in the presence of Me3Al, the (E)-isomer reacts significantly faster, leaving behind the Z-isomer intact at the end of the reaction. The presumed [LCo-H]+-intermediate, especially when L is a large-bite angle ligand, similar to DIOP and BDPP, promote an unusual isomerization of (E/Z)-mixtures of 1,3-dienes to isomerically pure Z-isomers. A mechanism that involves an intramolecular hydride addition via an [η4-(diene)(LCo-H)]+ complex, followed by p-s-p isomerization of the intermediate Co(allyl) species, is proposed for this reaction.