37881-09-7

Basic information

• Product Name: Ethanone, 1-[4-(1,1-dimethylethyl)-1-cyclohexen-1-yl]-
• CAS NO: 37881-09-7
• Molecular Formula: C12H20O
• Molecular Weight: 180.29
• Mol File: 37881-09-7.mol
• Article Data: 8

Chemical Properties

• CAS DataBase Reference: Ethanone, 1-[4-(1,1-dimethylethyl)-1-cyclohexen-1-yl]-(CAS DataBase Reference)
• NIST Chemistry Reference: Ethanone, 1-[4-(1,1-dimethylethyl)-1-cyclohexen-1-yl]-(37881-09-7)
• EPA Substance Registry System: Ethanone, 1-[4-(1,1-dimethylethyl)-1-cyclohexen-1-yl]-(37881-09-7)

Safety Data

• Hazardous Substances Data: 37881-09-7(Hazardous Substances Data)

Usage

General Description

Ethanone, 1-[4-(1,1-dimethylethyl)-1-cyclohexen-1-yl]- is a chemical compound with the formula C16H24O. It is primarily used in the production of fragrances and flavorings for the food and beverage industry. Ethanone, 1-[4-(1,1-dimethylethyl)-1-cyclohexen-1-yl]- is a ketone derivative and is often found in essential oils and aromatic plants. It has a pleasant, floral odor and is used in perfumes and scented products. Additionally, it is also used as a starting material in the synthesis of other organic compounds and as a flavoring agent in the food industry. Overall, it has a wide range of industrial applications due to its aromatic properties and chemical reactivity.

Upstream product

• 125950-34-7 1-(1-ethoxyvinyl)-4-tert-butylcylohex-1-ene 
• 83911-66-4 2-Benzenesulfonyl-6-tert-butyl-2-methyl-1-oxa-spiro[2.5]octane 
• 98-53-3 4-tercbutyl-cyclohexanone 
• 1066-54-2 trimethylsilylacetylene 
• 183598-09-6 4-tert-butyl-1-(trimethylsilylethynyl)cyclohexan-1-ol 
• 20325-03-5 4-(1,1-dimethylethyl)-1-ethynylcyclohexanol 
• 941-44-6 4-tert-butyl-1-hydroxy-cyclohexanecarbonitrile 
• 77412-96-5 1-trifluoromethanesulfonyloxy-4-t-butylcyclohexene 
• 201230-82-2 carbon monoxide 
• 111036-56-7 2-Benzenesulfinyl-6-tert-butyl-2-methyl-1-oxa-spiro[2.5]octane 
• 594-27-4 tetramethylstannane 
• 6556-05-4 1-ethynyl-t-4-tert-butylcyclohexan-r-1-ol 
• 7370-14-1 4-tert-butyl-1-cyanocyclohexene 
• 917-54-4 methyllithium 

Downstream Products

• 1599472-46-4 C₁₄H₂₄ 
• 1599472-47-5 C₁₄H₂₄ 
• 78187-29-8 C₁₂H₁₆⁽²⁾H₄O 
• 78187-29-8 C₁₂H₁₆⁽²⁾H₄O 
• 61674-99-5 2-(4-tert-Butyl-cyclohex-1-enyl)-but-3-en-2-ol 
• 22642-99-5 1-((1R,2S,4R)-4-tert-Butyl-2-methyl-cyclohexyl)-ethanone 
• 22642-99-5 1-((1S,2S,4R)-4-tert-Butyl-2-methyl-cyclohexyl)-ethanone 
• 41601-72-3 1-isopropenyl-4-t-butylcyclohexene 
• 41601-70-1 2-(4-tert-Butyl-cyclohex-1-enyl)-propan-2-ol 

Relevant articles and documents

Access to Cycloalkeno[ c]-Fused Pyridines via Pd-Catalyzed C(sp2)-H Activation and Cyclization of N-Acetyl Hydrazones of Acylcycloalkenes with Vinyl Azides

A novel Pd(II)-catalyzed vinylic C-H activation and cyclization has been developed, reacting a series of small, medium, and large N-acetyl hydrazones of acylcycloalkenes with vinyl azides to access diverse cycloalkeno[c]-fused pyridine scaffolds. This protocol provides progress in C(sp2)-H bond activation of medium to large cycloalkenes, and the target products can be obtained in a specific regioselectivity with good functional group tolerance and a broad substrate scope.

Mild conversion of propargylic alcohols to α,β-unsaturated enones in ionic liquids (ILs); A new 'metal free' life for the Rupe rearrangement

A mild and selective transition metal free protocol for the conversion of propargylic alcohols to cyclic and acyclic α,β-unsaturated enones via the Rupe rearrangement is reported. The method utilizes the Br?nsted acidic ionic liquid [BMIM-SO3H][OTf] as catalyst and [BMIM][PF 6] as solvent and offers the potential for recycling and reuse of the IL solvent. The feasibility to synthesize bicyclic fused cyclopentenone derivatives via a Rupe → Aldol → Nazarov sequence utilizing this protocol has also been demonstrated.

A Novel Synthesis of Methylenecyclopropane Spiro-Linked with Cycloalkanes via a Cyclization of Allylic Epoxides and Its Application to a Synthesis of Fused 3-Methylfurans

Ring closure of allylic epoxides derived from 1-chloroalkyl phenyl sulfoxides and cyclic ketones with lithium diisopropylamide (LDA) in 3-Exo-Tet mode gave spiro-linked methylenecyclopropanes having a hydroxyl group in good yields.Oxidation of these compounds gave ketones, which were then treated with p-toluenesulfonic acid in 1,4-dioxane or DMSO at 100 deg C to give fused 3-methylfurans in good overall yields.This procedure was applied to a synthesis of menthofuran from 4-methylcyclohexanone.