160016-01-3

Basic information

• Product Name: trans-diiodobis(trimethylsiloxyphenylisocyanide)palladium(II)
• CAS NO: 160016-01-3
• Molecular Weight: 742.839
• Mol File: 160016-01-3.mol

Chemical Properties

• CAS DataBase Reference: trans-diiodobis(trimethylsiloxyphenylisocyanide)palladium(II)(CAS DataBase Reference)
• NIST Chemistry Reference: trans-diiodobis(trimethylsiloxyphenylisocyanide)palladium(II)(160016-01-3)
• EPA Substance Registry System: trans-diiodobis(trimethylsiloxyphenylisocyanide)palladium(II)(160016-01-3)

Safety Data

• Hazardous Substances Data: 160016-01-3(Hazardous Substances Data)

Upstream product

• 86149-22-6 2-(trimethylsilyloxy)phenyl isocyanide 
• 7790-38-7 palladium(II) iodide 

Relevant articles and documents

Palladium(II) complexes with benzoxazol-2-ylidene ligands: Crystal structures of trans-chloro(benzoxazol-2-ylidene)-bis(triphenylphosphine) palladium(II) chloride and cis-diiodo(benzoxazol-2-ylidene)(triphenylphosphine) palladium(II)

The palladium(II) complexes trans-[PdCl(L)(PPh3)2]Cl, 5, and cis-[PdI2(L)PPh3], 7, (L = benzoxazol-2-ylidene) have been synthesized by treatment of the complexes trans-[PdX 2(PPh3)2] (4: X = Cl, 6: X = I) with 2-(trimethylsiloxy)phenyl isocyanide 1, and subsequent hydrolysis of the Si-O bond. The crystal structures of 5 and 7*CH2Cl2 were established by X-ray diffraction. NMR and IR studies indicate, that the unexpected cis-configuration of 7 obtained from trans-[PdI2(PPh 3)2] is not the result of a solution equilibrium between the cis- and the trans-isomers.