86149-22-6

Upstream product

• 273-53-0 benzoxazole 
• 75-77-4 chloro-trimethyl-silane 
• 90776-63-9 2-trimethylsiloxyformanilide 
• 503-38-8 trichloromethyl chloroformate 
• 2843-27-8 N-(2-hydroxyphenyl)formamide 

Downstream Products

• 833-50-1 2-phenylbenzo[d]oxazole 
• 150501-20-5 Fe(CO)4(CNC₆H₄OSi(CH₃)3) 
• 151834-41-2 pentacarbonyl(2-trimethylsiloxyphenyl isocyanide)tungsten⁽⁰⁾ 
• 164071-85-6 pentacarbonyl(2-hydroxyphenyl isocyanide)chromium⁽⁰⁾ 
• 170471-29-1 cis-tetrachlorobis(2-trimethylsiloxyphenyl isocyanide)titanium(IV) 
• 163776-02-1 [(CH₃)3SiOC₆H₄NC]3Fe(C₅H₅)⁽¹⁺⁾*Cl^(1-)=[(CH₃)3SiOC₆H₄NC]3Fe(C₅H₅)Cl 
• 173851-50-8 (2-(trimethylsiloxy)phenyl isocyanide) - triphenyl borane 
• 160016-01-3 trans-diiodobis(trimethylsiloxyphenylisocyanide)palladium(II) 
• 173851-47-3 1,4-bis(2-hydroxyphenyl)-2,2,3,5,5,6-hexaphenyl-2,5-dibora-2,5-dihydropyrazine 
• 173851-49-5 [(C₆H₅)2B]2(CNC₆H₄O)(OCNHC₆H₄OH)*CH₃OH*(CH₃)2CO 
• 186788-77-2 trans-[ReCl(2-(trimethylsiloxy)phenylisocyanide)(1,2-bis(diphenylphosphino)ethane)2] 

Relevant academic research and scientific papers

Synthesis of Heterobimetallic Complexes by Coordination of Rhodium(III) and Iridium(III) Poly-N,O-NHC Complexes to Silver(I), Copper(II), and Zinc(II)

The reaction of [RhCl2(Cp?)]2 with 2-trimethylsiloxyphenyl isocyanide (1) led to the mononuclear diisocyanide complex [RhCl(Cp?)(1)2]. Cleavage of the Si-O bonds of the coordinated isocyanide ligands with a catalytic amount of KF and H2O gave the neutral rhodium(III) complex [RhCl(Cp?)(NH,O-NHC)(N,O-NHC)] ([2]) bearing a C2-metalated N,O-benzoxazolinato ligand and an NH,O-benzoxazolin-2-ylidene ligand. In the presence of AgBF4 the same reaction sequence with [MCl2(Cp?)]2 (M = Rh, Ir) and 1 led to the removal of all halogeno ligands and formation of the complexes [M(Cp?)(NH,O-NHC)(N,O-NHC)2] (M = Rh, [3]; M = Ir, [4]) bearing one C-metalated NH,O-NHC benzoxazolin-2-ylidene and two C-metalated N,O-benzoxazolinato ligands. Deprotonation of the remaining N-H function in complexes [3] and [4] generated complexes with three amido donor functions which act as tripodal metalloligands for the coordination to additional transition metals such as AgI, CuII, and ZnII, thus allowing the preparation of the polynuclear heterobimetallic complexes [5]-[10] bearing C/N-metalated benzoxazolinato ligands.

Facile Synthesis of (1,2-Dihydrobenzoxazol-2-ylidene)tetracarbonyliron Complexes from 2-Trimethylsiloxyphenyl Isocyanide

Reaction of 2-trimethylsiloxyphenyl isocyanide 3 with Fe(CO)5 and subsequent cleavage of the Si-O bond gives (1,2-dihydrobenzoxazol-2-ylidene)tetracarbonyliron 6, the structure of which has been determined by X-ray crystallography; complex 6 can be alkylated at the ring nitrogen yielding (N-methyl-1,2-dihydrobenzoxazol-2-ylidene)tetracarbonyliron 7.

SYNTHESE VON BENZOXAZOL-2-YLTRIMETHYLSILAN UND -STANNAN

Metallation of benzoxazole with n-buthyllithium leads to two isomeric lithium compounds, which exist in a mobile equilibrium.Further reaction with trimethylchlorsilane yields 2-trimethylsiloxy-phenylisonitrile (II), with trimethylchlorostannane the benzoxazol-2-trimethylstannane (III) is obtained.The stannane III can be transferred to the benzoxazol-2-yltrimethylsilane (I) by reaction with trimethylchlorosilane.