1600519-44-5Relevant academic research and scientific papers
Visible-light-facilitated 5-exo-trig cyclization of 1,6-dienes with alkyl chlorides: Selective scission of the C(sp3)-H bond in alkyl chlorides
Liu, Yu,Zhang, Jia-Ling,Song, Ren-Jie,Li, Jin-Heng
, p. 1177 - 1181 (2014)
A general and conceptually novel method for preparing polychloro- substituted pyrrolidin-2-ones and indeno[2,1-c]pyrrol-3(3aH)-ones is established by visible-light-facilitated 5-exo-trig cyclization of 1,6-dienes with alkyl chlorides through selectively splitting the C(sp3)-H bond adjacent to the chloride atom to form an alkyl radical. The 5-exo-trig cyclization of 1,6-dienes with alkyl chlorides through a visible-light-facilitated radical strategy is presented. This is achieved by selectively splitting the C(sp 3)-H bond adjacent to the chloride atom to form an alkyl radical. bpy = 2,2′-bipyridyl. Copyright
