16006-20-5

Basic information

• Product Name: D-MYO-INOSITOL 4-MONOPHOSPHATE AMMONIUM SALT DI(CYCLOHEXYLAMMONIUM) SALT
• Synonyms: D-MYO-INOSITOL 4-MONOPHOSPHATE AMMONIUM SALT DI(CYCLOHEXYLAMMONIUM) SALT;D-MYO-INOSITOL-4-MONOPHOSPHATE BIS-CYCLOHEXYLAMMONIUM SALT;D-myo-inositol 4-monophosphate*di(cyclohexylammon;D-MYO-INOSITOL 4-MONOPHOSPHATE*DI(CYCLOH EXYLAMMONIU
• CAS NO: 16006-20-5
• Molecular Formula: 2C₆H₁₃N*C₆H₁₃O₉P
• Molecular Weight: 458.48
• Product Categories: Carbohydrates;Carbohydrates A to;Carbohydrates H-LBiochemicals and Reagents;Monosaccharide
• Mol File: 16006-20-5.mol
• Article Data: 6

Chemical Properties

• Appearance: /
• Storage Temp.: −20°C
• CAS DataBase Reference: D-MYO-INOSITOL 4-MONOPHOSPHATE AMMONIUM SALT DI(CYCLOHEXYLAMMONIUM) SALT(CAS DataBase Reference)
• NIST Chemistry Reference: D-MYO-INOSITOL 4-MONOPHOSPHATE AMMONIUM SALT DI(CYCLOHEXYLAMMONIUM) SALT(16006-20-5)
• EPA Substance Registry System: D-MYO-INOSITOL 4-MONOPHOSPHATE AMMONIUM SALT DI(CYCLOHEXYLAMMONIUM) SALT(16006-20-5)

Safety Data

• WGK Germany: 3
• Hazardous Substances Data: 16006-20-5(Hazardous Substances Data)

Upstream product

• 2831-74-5 D-myo-inositol-3-phosphate 
• 108-91-8 cyclohexylamine 
• 1447463-99-1 (1R,2r,3S,4R,5r,6S)-2,4,5,6-tetrakis((4-methoxybenzyl)oxy)cyclohexane-1,3-diol 
• 1447464-01-8 C₅₆H₅₉N₂O₁₃P 
• 132891-78-2 1,2;4,5-Di-O-cyclohexylidene-3-O-dibenzylphosphoryl-L-myo-inositol 
• 132891-77-1 6-O-Camphanoyl-1,2;4,5-di-O-cyclohexylidene-L-myo-inositol 
• 193285-10-8 D-1,2;4,5-di-O-cyclohexylidene-3-((2'S,4'S,5'R)-3',4'-dimethyl-5'-phenyl-1',3',2'-oxazaphospholidin-2'-one)-myo-inositol 
• 193285-11-9 Phosphoric acid (1R,2S)-2-methylamino-1-phenyl-propyl ester (1S,2S,3R,4S,5S,6S)-2,3,4,5,6-pentahydroxy-cyclohexyl ester 
• 114828-08-9 2,4,6-tri-O-benzyl-myo-inositol 
• 474404-92-7 (+)-2,4,6-tri-O-benzyl-myo-inositol-3-phosphate 
• 6763-49-1 (+/-)-1,2:5,6-dicyclohexylidene-myo-inositol 
• 140391-26-0 1-(1-(S)-camphanyl)-2,3:4,5-dicyclohexylidene-D-myo-inositol 
• 34361-60-9 1,2:4,5-dicyclohexylidene-myo-inositol 

Relevant articles and documents

Synthesis of unsymmetric diphospho-inositol polyphosphates

One to rule them all: A novel C2-symmetric phosphoramidite was developed that can be used to prepare all four unsymmetric diphospho inositol pentaphosphates (PP-InsP5). The target structures were synthesized in few steps and high enantiomeric ratios. With the obtained compounds, specificity of Ddp1 from yeast (a PP-InsP5 phosphatase) was studied. Copyright

Structure of (±)-1,2;4,5-di-o-cyclohexylidene myo-inositol and synthesis of myo-inositol 3-phosphate via its phosphorylation with (2R,4S,5R)-2-chloro-3,4-dimethyl-5-phenyl-1,3,2-oxazaphospholidin-2-one

The crystal structure of (±)-1,2;4,5-di-O-cyclohexylidene myo-inositol, refined to R = 2.9%, shows interestingly disordered (flip-flop) hydrogen bonding. The higher reactivity of the 1/3 positions (rather than 4/6) has been evaluated using semi-empirical calculations. This diol has been phosphorylated with (2R,4S,5R)-2-chloro-3,4-dimethyl-5-phenyl-1,3,2- oxazaphospholidin-2-one and the diastereoisomer derived from phosphorylation at the 3-position was isolated by crystallisation. Deprotection with TFA/H2O then H2/Pd-C afforded myo-inositol 3-phosphate in only four steps from myo- inositol.

GLYCOSYL-INOSITOL DERIVATIVES III. SYNTHESIS OF HEXOSAMINE-INOSITOL-PHOSPHATES RELATED TO PUTATIVE INSULIN MEDIATORS

The disaccharides related to glycosyl phosphatidyl inositol anchors of membrane proteins, 4-O-(2-amino-2-deoxy-α-D-glucopyranosyl)-D-myo-inositol-1-phosphate and 4-O-(2-amino-2-deoxy-α-D-galactopyranosyl)-D-chiro-inositol-1-phosphate, have been prepared from optically resolved myo-inositol derivatives.The chiro-inositol moiety was obtained by epimerization of a selectively blocked myo-inositol-triflate ester.The resolved inositols were subsequently phosphorylated to yield the disaccharide aglycones.The amino-sugar components were prepared by azidonitration of suitably protected glucal and galactal derivatives.The derived pyranosyl chlorides were then condensed with the inositol phosphates using silver triflate as the promoter.