160146-80-5

Basic information

• Product Name: (1S,7aR)-7a-Methyl-1-(2-methyl-[1,3]dioxolan-2-yl)-2,3,5,6,7,7a-hexahydro-1H-indene-4-carboxylic acid (1R,2S,5R)-5-methyl-2-(1-methyl-1-phenyl-ethyl)-cyclohexyl ester
• Synonyms: (1S,7aR)-7a-Methyl-1-(2-methyl-[1,3]dioxolan-2-yl)-2,3,5,6,7,7a-hexahydro-1H-indene-4-carboxylic acid (1R,2S,5R)-5-methyl-2-(1-methyl-1-phenyl-ethyl)-cyclohexyl ester
• CAS NO: 160146-80-5
• Molecular Weight: 480.688
• Mol File: 160146-80-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (1S,7aR)-7a-Methyl-1-(2-methyl-[1,3]dioxolan-2-yl)-2,3,5,6,7,7a-hexahydro-1H-indene-4-carboxylic acid (1R,2S,5R)-5-methyl-2-(1-methyl-1-phenyl-ethyl)-cyclohexyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: (1S,7aR)-7a-Methyl-1-(2-methyl-[1,3]dioxolan-2-yl)-2,3,5,6,7,7a-hexahydro-1H-indene-4-carboxylic acid (1R,2S,5R)-5-methyl-2-(1-methyl-1-phenyl-ethyl)-cyclohexyl ester(160146-80-5)
• EPA Substance Registry System: (1S,7aR)-7a-Methyl-1-(2-methyl-[1,3]dioxolan-2-yl)-2,3,5,6,7,7a-hexahydro-1H-indene-4-carboxylic acid (1R,2S,5R)-5-methyl-2-(1-methyl-1-phenyl-ethyl)-cyclohexyl ester(160146-80-5)

Safety Data

• Hazardous Substances Data: 160146-80-5(Hazardous Substances Data)

Upstream product

• 7381-30-8 2,2,7,7-tetramethyl-3,6-dioxa-2,7-disilaoctane 
• 160146-79-2 (1S,7aR)-1-Acetyl-7a-methyl-2,3,5,6,7,7a-hexahydro-1H-indene-4-carboxylic acid (1R,2S,5R)-5-methyl-2-(1-methyl-1-phenyl-ethyl)-cyclohexyl ester 
• 160146-75-8 (S)-7a-Methyl-1-oxo-2,3,5,6,7,7a-hexahydro-1H-indene-4-carboxylic acid (1R,2S,5R)-5-methyl-2-(1-methyl-1-phenyl-ethyl)-cyclohexyl ester 
• 160146-84-9 (1R,7aS)-1-Isopropenyl-1-methoxycarbonyloxy-7a-methyl-2,3,5,6,7,7a-hexahydro-1H-indene-4-carboxylic acid (1R,2S,5R)-5-methyl-2-(1-methyl-1-phenyl-ethyl)-cyclohexyl ester 
• 160146-77-0 (1R,7aS)-1-Hydroxy-1-isopropenyl-7a-methyl-2,3,5,6,7,7a-hexahydro-1H-indene-4-carboxylic acid (1R,2S,5R)-5-methyl-2-(1-methyl-1-phenyl-ethyl)-cyclohexyl ester 
• 1026419-40-8 Methanesulfonic acid 3-(6-methyl-1,4,8,11-tetraoxa-dispiro[4.1.4.2]tridec-6-yl)-propyl ester 
• 160146-87-2 7a-Methyl-1-oxo-2,3,5,6,7,7a-hexahydro-1H-indene-4-carboxylic acid allyl ester 
• 1027968-80-4 7a-Methyl-1-oxo-2,3,5,6,7,7a-hexahydro-1H-indene-4-carbonyl chloride 
• 160146-88-3 7a-Methyl-1-oxo-2,3,5,6,7,7a-hexahydro-1H-indene-4-carboxylic acid 
• 160146-76-9 6-methyl-6-(3-iodopropyl)-1,4,8,11-tetraoxadispiro[4.1.4.2]tridecane 
• 1026628-33-0 3-(6-Methyl-1,4,8,11-tetraoxa-dispiro[4.1.4.2]tridec-6-yl)-propan-1-ol 
• 65253-04-5 (-)-8-phenylmenthol 
• 26828-48-8 2-allyl-2-methyl-1,3-cyclopentanedione 
• 70833-73-7 6-allyl-6-methyl-1,4,8,11-tetraoxadispiro[4.1.4.2]tridecane 

Downstream Products

• 160146-85-0 Benzoic acid (1S,4R,7aR)-7a-methyl-1-(2-methyl-[1,3]dioxolan-2-yl)-2,4,5,6,7,7a-hexahydro-1H-inden-4-ylmethyl ester 
• 1027563-72-9 Benzoic acid (1S,3aS,4R,7aS)-7a-methyl-1-(2-methyl-[1,3]dioxolan-2-yl)-octahydro-inden-4-ylmethyl ester 
• 160146-81-6 (1S,4R,7aR)-7a-Methyl-1-(2-methyl-[1,3]dioxolan-2-yl)-2,4,5,6,7,7a-hexahydro-1H-indene-4-carboxylic acid (1R,2S,5R)-5-methyl-2-(1-methyl-1-phenyl-ethyl)-cyclohexyl ester 

Relevant articles and documents

A new candidate for a properly substituted CD ring component of vitamin D3 via intramolecular asymmetric olefination of a 1,3-cyclopentanedione derivative

A highly diastereoselective synthesis of hydrindenone derivative 5 (98% de) was achieved via diastereotopic differentiation of 1,3-cyclopentanedione derivative 4 by intramolecular Horner-Emmons olefination. In addition, the compound 5 was converted to ketone 2, a new building block for 1α,25-dihydroxyvitamin D3 (1).