1601476-96-3Relevant academic research and scientific papers
Enantioselective rhodium-catalysed insertion of trifluorodiazoethanes into tin hydrides
Hyde, Stephen,Veliks, Janis,Ascough, David M.H.,Szpera, Robert,Paton, Robert S.,Gouverneur, Véronique
, p. 17 - 25 (2019)
Aryl substituted 2,2,2-trifluorodiazoethanes undergo rhodium(II)-catalysed insertion reactions with tin hydrides affording the corresponding α-(trifluoromethyl)benzyl stannanes. This reactivity contrasts with that of diazo esters which predominantly afford CH2 reduction products in the presence of tin hydrides. The first example of asymmetric insertion into tin hydrides using diazo compounds is also described. In addition, this system extends to asymmetric germanium hydride and silane insertion.
Pd-carbene migratory insertion: Application to the synthesis of trifluoromethylated alkenes and dienes
Wang, Xi,Xu, Yan,Deng, Yifan,Zhou, Yujing,Feng, Jiajie,Ji, Guojing,Zhang, Yan,Wang, Jianbo
supporting information, p. 961 - 965 (2014/02/14)
Pd-catalyzed cross-coupling of halides with CF3-substituted diazo compounds or N-tosylhydrazones has been explored for the synthesis of CF3-substituted alkenes and 1,3-butadienes. Pd-carbene migratory insertion plays the key role in these transformations. Copyright
