16023-50-0Relevant academic research and scientific papers
Carbothioamide as Highly Efficient Ligand for Copper-catalyzed Room Temperature Chan–Lam Cross-Coupling Reaction
Baruah, Jayantajit,Gogoi, Kongkona,Dewan, Anindita,Borah, Geetika,Bora, Utpal
, p. 1203 - 1208 (2017)
The catalytic activity of three N,S-donor ligands, viz L1 [2-(4-methoxybenzylidene)-N-phenylhydrazinecarbothioamide], L2 [2,2′-(1,2-diphenylethane-1,2-diylidene)bis(hydrazinecarbothioamide)] and L3 [2-(4-methoxybenzylidene)hydrazinecarbothioamide] has been reported for N-arylation of imidazoles with arylboronic acids in ethanol at room temperature. The method was found to be applicable in N-arylation for a wide range of electronically diverse arylboronic acids with imidazoles having modest to excellent isolated yields. The in situ generated copper(II) complex of the ligand namely, 2-(4-methoxybenzylidene)-N-phenylhydrazinecarbothioamide (L1) was found to be highly efficient homogeneous catalyst for N-arylation reaction.
Synthesis and characterization of Palladium(II) complexes with thiosemicarbazones
Sultana, Samim,Baruah, Jayantajit,Borah, Geetika
, p. 1205 - 1208 (2018)
Three new complexes viz., [PdCl2(H-aatp)2] (1), [Pd(dmbptz)2] (2) and [Pd(btz)] (3) have been synthesized by reacting [PdCl2(cod)] with the ligands H-aatp, H-dmbptz and H2-btz, respectively (where H-aatp = anisa
Transition metal complexes of dis(thiosemicarbazone): Synthesis and spectral, and antifungal studies
Refat, Moamen S.,Chandra, Sulekh,Tyagi, Monika
, p. 22 - 33 (2010)
Mn(II), Co(II), Ni(II), and Cu(II) complexes have been synthesized with benzil bis(thiosemicarbazone) (L) and characterized by elemental analyses, molar conductance measurements, magnetic susceptibility measurements, thermogravimetric studies, infrared (I
Heteronuclear NMR Spectroscopic Investigations of Gallium Complexes of Substituted Thiosemicarbazones Including X-Ray Crystal Structure, a New Halogen Exchange Strategy, and 18F Radiolabelling
Venkatachalam,Pierens,Bernhardt, Paul V.,Stimson,Bhalla,Lambert,Reutens
, p. 1033 - 1048 (2016)
Five thiosemicarbazone ligands have been synthesized, and their coordination chemistry with gallium was investigated. The reaction of these thiosemicarbazones with gallium chloride in alcohol solutions in the presence of a base yielded the corresponding p
Synthesis of 18F-radiolabeled diphenyl gallium dithiosemicarbazone using a novel halogen exchange method and in vivo biodistribution
Venkatachalam, Taracad K.,Stimson, Damion H.R.,Bhalla, Rajiv,Mardon, Karine,Bernhardt, Paul V.,Reutens, David C.
, p. 321 - 331 (2019)
18F-radiolabeled diphenyl gallium thiosemicarbazone was prepared by [18F] fluoride exchange of a nitrato anion under mild conditions. The diphenyl gallium thiosemicarbazone chloride is easily prepared in gram quantities and can be us
