Hydrazinecarbothioamide, 2,2'-(1,2-diphenyl-1,2-ethanediylidene)bis-

Base Information

• Chemical Name: Hydrazinecarbothioamide, 2,2'-(1,2-diphenyl-1,2-ethanediylidene)bis-
• CAS No.: 16023-50-0
• Molecular Formula: C16H16N6S2
• Molecular Weight: 356.475
• DSSTox Substance ID: DTXSID10425028
• Mol file: 16023-50-0.mol

Synonyms:Benzildithiosemicarbazone;16023-50-0;CBDivE_005642;SCHEMBL23160872;DTXSID10425028;Hydrazinecarbothioamide, 2,2'-(1,2-diphenyl-1,2-ethanediylidene)bis-

Chemical Property of Hydrazinecarbothioamide, 2,2'-(1,2-diphenyl-1,2-ethanediylidene)bis-

Chemical Property:

• XLogP3: 2.5
• Hydrogen Bond Donor Count: 4
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 5
• Exact Mass: 356.08778688
• Heavy Atom Count: 24
• Complexity: 459

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC=C(C=C1)C(=NNC(=S)N)C(=NNC(=S)N)C2=CC=CC=C2

Technology Process of Hydrazinecarbothioamide, 2,2'-(1,2-diphenyl-1,2-ethanediylidene)bis-

There total 1 articles about Hydrazinecarbothioamide, 2,2'-(1,2-diphenyl-1,2-ethanediylidene)bis- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 78.0%

thiosemicarbazide (79-19-6) + benzil (134-81-6) → benzil bis(thiosemicarbazone) (16023-50-0)

Guidance literature:

With hydrogenchloride; In ethanol; at 65 ℃; for 3h;

DOI:10.14233/ajchem.2018.21117

Reference yield: 95.0%

zinc(II) nitrate hexahydrate + benzil bis(thiosemicarbazone) (16023-50-0) → [Zn(benzylbis(thiasemicarbazone-2H)](n) (53277-00-2)

Guidance literature:

With LiOH*H₂O; In ethanol; a soln. of Zn-salt in ethanol was added to a suspn. of semicarbazone-compound and LiOH*H2O in ethanol, the mixt. was stirred under reflux for 6 h; solid was filtered off, washed with methanol, vac.-dried; elem. anal.;

DOI:10.1021/ic035461a

Reference yield: 95.0%

benzil bis(thiosemicarbazone) (16023-50-0) + tin(IV) chloride (7646-78-8) → [Sn(benzil bis(thiosemicarbazone)Cl2][SnCl6] (1093077-04-3)

Guidance literature:

In dichloromethane; (Ar); SnCl4 in CH2Cl2 added over a suspn. of organic ligand; stirred at room temp. for 12 h; filtered off; washed with CH2Cl2; dried in vacuo; elem. anal.;

DOI:10.1002/zaac.200700299

upstream raw materials:

thiosemicarbazide

benzil

Downstream raw materials:

(benzilbisthiosemicarbazonide)copper(II)

Ni((C₆H₅CNNHC(S)NH)2)

Cu(benzilbisthiosemicarbazone)Cl

Cu(benzilbisthiosemicarbazone)