1602485-07-3Relevant academic research and scientific papers
Copper-Catalyzed Three-Component Azidotrifluoromethylation/Difunctionalization of Alkenes
Yang, Mingbo,Wang, Wenlu,Liu, Yin,Feng, Lijie,Ju, Xuexia
, p. 833 - 837 (2015)
A novel three-component strategy for the azidotrifluoromethylation of alkenes has been presented here. The reaction proceeded smoothly under gentle temperature and gave the bifunctional olefins in high yields. Furthermore, 1,3-dipolar reactions between az
Copper-catalyzed intermolecular trifluoromethylazidation of alkenes: Convenient access to CF3-containing alkyl azides
Wang, Fei,Qi, Xiaoxu,Liang, Zhaoli,Chen, Pinhong,Liu, Guosheng
supporting information, p. 1881 - 1886 (2014/03/21)
A novel copper-catalyzed intermolecular trifluoromethylazidation of alkenes has been developed under mild reaction conditions. A variety of CF 3-containing organoazides were directly synthesized from a wide range of olefins, including activated and unactivated alkenes, and the resulting products can be easily transformed into the corresponding CF3- containing amine derivatives. The title reaction proceeds with a CF 3+ reagent under mild reaction conditions. This transformation presents a broad substrate scope and good functional-group tolerance. A variety of CF3-containing organoazides are directly synthesized from a wide range of olefins, including activated and unactivated alkenes. The resulting products are easily transformed into the corresponding amine derivatives. Copyright
