1602485-37-9Relevant articles and documents
Synthesis of β-Trifluoromethylated Alkyl Azides via a Manganese-Catalyzed Trifluoromethylazidation of Alkenes with CF3SO2Na and TMSN3
Zhang, Yuecheng,Han, Xulin,Zhao, Jiquan,Qian, Zijian,Li, Tianmei,Tang, Yuqing,Zhang, Hong-Yu
supporting information, p. 2659 - 2667 (2018/05/30)
A convenient and efficient manganese-catalyzed trifluoromethylazidation of alkenes has been developed by utilizing inexpensive and readily available CF3SO2Na under mild conditions. The various β-trifluoromethylated alkyl azides were
Copper-catalyzed intermolecular trifluoromethylazidation of alkenes: Convenient access to CF3-containing alkyl azides
Wang, Fei,Qi, Xiaoxu,Liang, Zhaoli,Chen, Pinhong,Liu, Guosheng
supporting information, p. 1881 - 1886 (2014/03/21)
A novel copper-catalyzed intermolecular trifluoromethylazidation of alkenes has been developed under mild reaction conditions. A variety of CF 3-containing organoazides were directly synthesized from a wide range of olefins, including activated and unactivated alkenes, and the resulting products can be easily transformed into the corresponding CF3- containing amine derivatives. The title reaction proceeds with a CF 3+ reagent under mild reaction conditions. This transformation presents a broad substrate scope and good functional-group tolerance. A variety of CF3-containing organoazides are directly synthesized from a wide range of olefins, including activated and unactivated alkenes. The resulting products are easily transformed into the corresponding amine derivatives. Copyright