1603-55-0

Basic information

• Product Name: CYCLOHEXENE-D10
• Synonyms: CYCLOHEXENE-D10
• CAS NO: 1603-55-0
• Molecular Formula: C₆H₁₀
• Molecular Weight: 92.21
• Mol File: 1603-55-0.mol
• Article Data: 3

Chemical Properties

• Melting Point: −104 °C(lit.)
• Boiling Point: 83 °C(lit.)
• Flash Point: 10 °F
• Appearance: /
• Density: 0.908 g/mL at 25 °C
• Refractive Index: n20/D 1.442(lit.)
• CAS DataBase Reference: CYCLOHEXENE-D10(CAS DataBase Reference)
• NIST Chemistry Reference: CYCLOHEXENE-D10(1603-55-0)
• EPA Substance Registry System: CYCLOHEXENE-D10(1603-55-0)

Safety Data

• Hazard Codes: F,Xi,Xn
• Statements: 11-36/37/38-21/22
• Safety Statements: 16-26-36/37/39-36/37-33-29
• RIDADR: UN 2256 3/PG 2
• WGK Germany: 3
• Hazardous Substances Data: 1603-55-0(Hazardous Substances Data)

Upstream product

• 110-83-8 cyclohexene 

Downstream Products

• 100311-45-3 trans-1,2-dibromocyclohexane-d₁₀ 
• 84248-95-3 1-(cyclohex-2-en-1-ylethynyl)benzene 
• 930-68-7 cyclohexenone 
• 286-20-4 cyclohexane-1,2-epoxide 
• 822-67-3 Cyclohex-2-enol 
• 38574-14-0 1,3,5-trimethyl<2,4,6-(2)H3>benzene 
• 20329-91-3 d₅-n-butylbenzene 
• 1421357-44-9 C₁₆H₁₃⁽²⁾H₉ 

Relevant articles and documents

Pd- η3-C6H9 complexes of the Trost modular ligand: High nuclearity columnar aggregation controlled by concentration, solvent and counterion

Under optimised conditions, the Trost modular ligand (TML) series induces high levels of asymmetric induction in an extraordinarily wide range of reactions involving palladium π-allyl intermediates. Prior mechanistic investigations into reactions involving Pd-η3-C6H9 intermediates have focussed on the monomeric 13-membered ring formed via P,P-chelation of the ligand to Pd. However, it is also recognised that ring-opening oligomerisation provides a pool of high nuclearity Pd-η3-C6H9 species that, by affording a low level, or even the opposite sense, of asymmetric induction relative to the mononuclear species, are responsible for a reduction in selectivity under non-optimised conditions. Herein we describe an investigation by NMR spectroscopy, molecular mechanics, molecular dynamics, and small-angle neutron scattering (SANS), of a Pd-η3-C6H9 cation bearing the 1,2-diaminocyclohexane TML ligand (2). Using both nondeuterated and perdeuterated (D47) isotopologues of the resulting complexes ([1]+), we show that a two-stage oligomerisation-aggregation process forms self assembled cylindrical aggregates of very high nuclearity (up to 56 Pd centres). We also investigate how concentration, solvent and counter-anion all modulate the extent of oligomerisation.

Protium-deuterium exchange of cyclic and acyclic alkanens in dilute acid medium at elevated temperatures

A modification of the high temperature - dilute acid (HTDA) method for deuterium labelling of aromatic compounds has been applied to the H-D exchange of a number of cyclic and acyclic alkenes.Cyclopentene, cyclohexene, cyclododecene, and tetramethylethylene have been completely exchanged in excellent yield. 1-Methylcyclopentene and 1-methylcyclohexene have also been perdeuterated and cycloheptene and cyclooctene partially labelled but require spinning band distillation or preparative glpc for separation from rearrangement products.A variety of C5-C8 acyclic alkeneshave also been treated under HTDA conditions.