160318-53-6

Upstream product

• 79218-68-1 2-O-acetyl-3,4,6-tri-O-benzyl-D-glucopyranose 
• 93125-77-0 (2R,3R,4R,5S)-1,3,4-tris(benzyloxy)hept-6-ene-2,5-diol 
• 384819-72-1 2-O-acetyl-3,4,6-tri-O-benzyl-D-glucono-1,5-lactone 
• 51532-75-3 3,4,6-tri-O-benzyl-1,2-O-(1-methoxyethylidene)-α-D-glucopyranose 
• 160318-52-5 (2S,3R,4R,5R,6R)-4,5-bis(benzyloxy)-6-((benzyloxy)methyl)-2-(iodomethyl)tetrahydro-2H-pyran-3-ol 

Downstream Products

• 384819-83-4 C₅₅H₆₀O₁₀ 
• 384819-81-2 C₅₅H₆₀O₁₀ 
• 384819-77-6 (2R,4aR,6R,7R,8R,8aS)-8-((2S,3S,4R,5R,6R)-4,5-Bis-benzyloxy-6-benzyloxymethyl-3-hydroxy-tetrahydro-pyran-2-ylmethyl)-6-methoxy-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-7-ol 
• 384819-75-4 ((3R,4S,5R,6R)-4,5-Bis-benzyloxy-6-benzyloxymethyl-2-methylene-tetrahydro-pyran-3-yloxy)-((2R,4aR,6R,7S,8R,8aR)-8-iodo-6-methoxy-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-7-yloxy)-dimethyl-silane 

Relevant academic research and scientific papers

Synthesis and spontaneous dimerization of the tri-O-benzyl derivative of ''2-keto-1-C-methylene-D-glucopyranose'' (2,6-anhydro-4,5,7-tri-O-benzyl-1-deoxy-D-arabino-hept-1-en-3-ulose)

In the synthetic studies on methylene-bridged disaccharide analogues (C-disaccharides), the coupling of '2-keto-1-C-methylene hexopyranose' derivatives have been considered by a way of a free-radical chain mechanism to provide a novel approach to 'linear'

Expedient and versatile formation of novel amino-deoxy-ketoheptuloses

Novel monoketoheptuloses have been synthesized employing an amination step in a pre- and/or post-C1 chain elongation using a Petasis reagent by starting from aldohexoses or aldohexosamines. A series of gluco and manno configured 1-/3-deoxy-1-/3-amino-keto

Selective radical synthesis of β-C-disaccharides

Several β-C-disaccharides have been selectively synthesized by radical cyclization of two temporarily tethered functionalized monosaccharides. In this process, intramolecular addition of a carbohydrate-derived radical onto an anomeric exomethylene group,