Synthesis and spontaneous dimerization of the tri-O-benzyl derivative of ''2-keto-1-C-methylene-D-glucopyranose'' (2,6-anhydro-4,5,7-tri-O-benzyl-1-deoxy-D-arabino-hept-1-en-3-ulose)

Article abstract of DOI:10.1016/0008-6215(94)00191-X

In the synthetic studies on methylene-bridged disaccharide analogues (C-disaccharides), the coupling of '2-keto-1-C-methylene hexopyranose' derivatives have been considered by a way of a free-radical chain mechanism to provide a novel approach to 'linear'