1603838-00-1

Basic information

• Product Name: 4-(4-chlorophenyl)-2-methyl-6-phenylphenanthridine
• Synonyms: 4-(4-chlorophenyl)-2-methyl-6-phenylphenanthridine
• CAS NO: 1603838-00-1
• Molecular Weight: 379.889
• Mol File: 1603838-00-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 4-(4-chlorophenyl)-2-methyl-6-phenylphenanthridine(CAS DataBase Reference)
• NIST Chemistry Reference: 4-(4-chlorophenyl)-2-methyl-6-phenylphenanthridine(1603838-00-1)
• EPA Substance Registry System: 4-(4-chlorophenyl)-2-methyl-6-phenylphenanthridine(1603838-00-1)

Safety Data

• Hazardous Substances Data: 1603838-00-1(Hazardous Substances Data)

Upstream product

• 42308-28-1 2-amino-5-methylbiphenyl 
• 1603837-88-2 4-chloro-2'-isocyano-5'-methyl-1,1':3',1''-terphenyl 
• 62-53-3 aniline 
• 1603837-73-5 3-bromo-2-isocyano-5-methyl-1,1'-biphenyl 
• 1140969-95-4 2-bromo-4-methyl-6-phenylaniline 
• 1679-18-1 4-Chlorophenylboronic acid 
• 6968-24-7 2,6-Dibromo-4-methylaniline 

Relevant articles and documents

Arylative cyclization of 2-isocyanobiphenyls with anilines: One-pot synthesis of 6-arylphenanthridines via competitive reaction pathways

A transition-metal-free method for the synthesis of C6 phenanthridine derivatives by arylative cyclization of 2-isocyanobiphenyls with arylamines in one pot was developed. Mechanistic studies suggest that electrophilic aromatic substitution (SEAr) of a nitrilium intermediate and homolytic aromatic substitution (HAS) of an imidoyl radical intermediate are two competitive reaction pathways involved in the annulation step.