160389-33-3Relevant academic research and scientific papers
Cyclopentadiene-, Furan- and Thiophene-derived 1,2-Dioxolene Complexes of Platinum(II) and the Crystal Structure of
Daldy, Julia A.,Fawcett, John,Henderson, William,Kemmitt, Raymond D. W.,Russell, David R.
, p. 3383 - 3388 (1994)
The synthesis of a number of platinum(II)-dioxolene complexes of the type was readily achieved in high yields via the silver(I) oxide-mediated reactions of the cyclic α,β-diketone compounds (X = CH2, O or S) with platinum(II) chloride complexes cis- 2 = cycloocta-1,5-diene (cod)>.The complexes can be considered to be derived from cyclopentadiene, furan or thiophene, and are related to metal-catecholates.A single-crystal structure determination on the cyclopentadiene-derived complex revealed the presence of a planar platinum-oxolene ring system.Silver(I) oxide can also be used to synthesise the related tetrachlorocatecholato complexes (L = PPh3 or L2 = cod) in high yields and purities.
