Cyclopentadiene-, Furan- and Thiophene-derived 1,2-Dioxolene Complexes of Platinum(II) and the Crystal Structure of

DOI: 10.1039/DT9940003383

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 3383 - 3388 (1994)

Update date:2022-08-03

Topics:

Authors:

Daldy, Julia A.

Fawcett, John

Henderson, William

Kemmitt, Raymond D. W.

Russell, David R.

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Article abstract of DOI:10.1039/DT9940003383

The synthesis of a number of platinum(II)-dioxolene complexes of the type was readily achieved in high yields via the silver(I) oxide-mediated reactions of the cyclic α,β-diketone compounds (X = CH2, O or S) with platinum(II) chloride complexes cis- 2 = cycloocta-1,5-diene (cod)>.The complexes can be considered to be derived from cyclopentadiene, furan or thiophene, and are related to metal-catecholates.A single-crystal structure determination on the cyclopentadiene-derived complex revealed the presence of a planar platinum-oxolene ring system.Silver(I) oxide can also be used to synthesise the related tetrachlorocatecholato complexes (L = PPh3 or L₂ = cod) in high yields and purities.

Full text of DOI:10.1039/DT9940003383

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