Welcome to LookChem.com Sign In|Join Free

Article Doi

Cyclopentadiene-, Furan- and Thiophene-derived 1,2-Dioxolene Complexes of Platinum(II) and the Crystal Structure of

DOI: 10.1039/DT9940003383

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 3383 - 3388 (1994)

Update date:2022-08-03

Topics:

Authors:

Daldy, Julia A.Daldy, Julia A.

Fawcett, JohnFawcett, John

Henderson, WilliamHenderson, William

Kemmitt, Raymond D. W.Kemmitt, Raymond D. W.

Russell, David R.Russell, David R.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/DT9940003383

The synthesis of a number of platinum(II)-dioxolene complexes of the type was readily achieved in high yields via the silver(I) oxide-mediated reactions of the cyclic α,β-diketone compounds (X = CH2, O or S) with platinum(II) chloride complexes cis- 2 = cycloocta-1,5-diene (cod)>.The complexes can be considered to be derived from cyclopentadiene, furan or thiophene, and are related to metal-catecholates.A single-crystal structure determination on the cyclopentadiene-derived complex revealed the presence of a planar platinum-oxolene ring system.Silver(I) oxide can also be used to synthesise the related tetrachlorocatecholato complexes (L = PPh3 or L2 = cod) in high yields and purities.

View More

Products guided by the article

Product name:Pt(OCC(CO2CH3)CH2C(CO2CH3)CO)(P(C6H5)3)2

Cas No:160389-33-3

160389-33-3

R&D Labs maybe for 160389-33-3

Relevant to this article

Hot Product