160437-02-5

Basic information

• Product Name: methyl 2-O-benzyl-6-deoxy-3,4-O-isopropylidene-β-L-arabino-hex-5-enopyranoside
• Synonyms: methyl 2-O-benzyl-6-deoxy-3,4-O-isopropylidene-β-L-arabino-hex-5-enopyranoside
• CAS NO: 160437-02-5
• Molecular Weight: 306.359
• Mol File: 160437-02-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: methyl 2-O-benzyl-6-deoxy-3,4-O-isopropylidene-β-L-arabino-hex-5-enopyranoside(CAS DataBase Reference)
• NIST Chemistry Reference: methyl 2-O-benzyl-6-deoxy-3,4-O-isopropylidene-β-L-arabino-hex-5-enopyranoside(160437-02-5)
• EPA Substance Registry System: methyl 2-O-benzyl-6-deoxy-3,4-O-isopropylidene-β-L-arabino-hex-5-enopyranoside(160437-02-5)

Safety Data

• Hazardous Substances Data: 160437-02-5(Hazardous Substances Data)

Upstream product

• 160437-03-6 methyl 2-O-benzyl-3,4-O-isopropylidene-6-O-trifluoromethylsulfonyl-α-D-galactopyranoside 
• 27851-16-7 methyl 2-O-benzyl-3,4-O-isopropylidene-α-D-galactopyranoside 

Downstream Products

• 1063665-55-3 ethyl (1S,2R,3a'R,6'S,7'R,7a'S)-7'-benzyloxy-6'-methoxy-2',2'-dimethyltetrahydrospiro[cyclopropane-1,4'-[1,3]dioxolo[4,5-c]pyran]-2-carboxylate 
• 1063665-53-1 ethyl (1S,2S,3a'R,6'S,7'R,7a'S)-7'-benzyloxy-6'-methoxy-2',2'-dimethyltetrahydrospiro[cyclopropane-1,4'-[1,3]dioxolo[4,5-c]pyran]-2-carboxylate 
• 1063665-50-8 ethyl (1R,2R,3a'R,6'S,7'R,7a'S)-7'-benzyloxy-6'-methoxy-2',2'-dimethyltetrahydrospiro[cyclopropane-1,4'-[1,3]dioxolo[4,5-c]pyran]-2-carboxylate 
• 1063665-52-0 ethyl (1R,2S,3a'R,6'S,7'R,7a'S)-7'-benzyloxy-6'-methoxy-2',2'-dimethyltetrahydrospiro[cyclopropane-1,4'-[1,3]dioxolo[4,5-c]pyran]-2-carboxylate 
• 1063665-32-6 (3a'R,6'S,7'R,7a'S)-7'-benzyloxy-6'-methoxy-2',2'-dimethyltetrahydrospiro[cyclopropane-1,4'-[1,3]dioxolo[4,5-c]pyran] 
• 1063665-41-7 (1S,3a'R,6'S,7'R,7a'S)-7'-benzyloxy-2,2-dichloro-6'-methoxy-2',2'-dimethyltetrahydrospiro[cyclopropane-1,4'-[1,3]dioxolo[4,5-c]pyran] 

Relevant articles and documents

Fluorination at position 6 of derivatives of methyl α-D-galactopyranoside

The present work requires deoxy and deoxyfluoro analogues of methyl α-D-galactopyranoside and of the methyl α-glycoside. Methyl 6-deoxy-6-fluoro-3, 4-O-isopropylidene-α-D-galactopyranoside is used to prepare the 6-deoxy-6-fluoro derivative of the dissacharide as the glycosyl acceptor in the condensation reaction.