160481-55-0Relevant academic research and scientific papers
Light-mediated dual phosphine-/copper-catalyzed atom transfer radical addition reaction
Fedorov, Oleg V.,Scherbinina, Sofya I.,Levin, Vitalij V.,Dilman, Alexander D.
, p. 11068 - 11079 (2019)
The atom transfer radical addition reaction catalyzed by triphenylphosphine and copper(I) halide is described. The reaction proceeds under irradiation with 365 nm light using a light-emitting diode and was performed in regular glassware. The proposed mech
-Thia-Wittig Rearrangements of α-Lithiated Sulfides Via De-aromatized Cyclohexadiene Intermediates Proceed with Inversion of Configuration at the Carbanionic Center
Brickmann, Kay,Hambloch, Frank,Spolaore, Emanuela,Brueckner, Reinhard
, p. 1949 - 1958 (2007/10/02)
The nBuLi-induced tin/lithium exchange reactions of the diastereomeric γ--α-(tributylstannyl) sulfides anti- and syn-8 delivered the α-(lithioalkyl) benzyl sulfides anti- and syn-11, respectively.Within 1 h at -78 deg C, these spec
