1605-19-2Relevant academic research and scientific papers
Direct synthesis of 1,1-diarylalkenes from alkenyl phosphates via nickel(0)-catalysed Suzuki-Miyaura coupling
Hansen, Anders L.,Ebran, Jean-Philippe,Gogsig, Thomas M.,Skrydstrup, Troels
, p. 4137 - 4139 (2007/10/03)
A combination of Ni(COD)2 and PCy3 promotes effectively the Suzuki-Miyaura cross coupling of 1-arylalkenyl phosphates with aryl boronic acids with yields attaining 99%. The Royal Society of Chemistry 2006.
Electron delocalization in cross-conjugated p-phenylenevinylidene oligomers
Klokkenburg, Mark,Lutz, Martin,Spek, Anthony L.,Van der Maas, John H.,Van Walree, Cornelis A.
, p. 3544 - 3554 (2007/10/03)
The synthesis, structure, and electronic properties of a series of cross-conjugated p-phenylenevinylidene oligomers with one to four double bonds are reported. The X-ray crystal structure of the compound with two double bonds reveals a nonplanar conformat
Multifunctional lithium containing initiator
-
, (2008/06/13)
Highly desirable multifunctional lithium containing initiators are prepared by reacting a compound such as an organo lithium with an organic compound containing at least two 1,1-diphenylethylene groups. Such initiators can be prepared in the absence of polar solvents and are very desirable for the polymerization of dienes such as butadiene to a desirable 1,4 configuration. Several di-lithium compounds have been employed to initiate polymerization of various unsaturated organic monomers.
