16053-58-0Relevant articles and documents
Wagner, F. C.,Reid, E. E.
, p. 3407 - 3413 (1931)
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Marvel,Helfrick,Belsley
, p. 1272 (1929)
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Takata et al.
, p. 821,823,824 (1979)
Chloride triggered reversible switching from a metallosupramolecular [Pd2L4]4+ cage to a [Pd2L2Cl4] metallo-macrocycle with release of endo- and exo-hedrally bound guests
Preston, Dan,Fox-Charles, Alyssa,Lo, Warrick K. C.,Crowley, James D.
supporting information, p. 9042 - 9045 (2015/05/27)
A metallosupramolecular [Pd2L4]4+ cage can be cleanly converted into a [Pd2L2Cl4] metallo-macrocycle upon addition of chloride ions. The process is reversible, treatment of the [Pd2L2Cl4] macrocycle with silver(i) ions regenerates the [Pd2L4]4+ cage. Additionally, it is shown that guest molecules could be released on chloride triggered cage dis-assembly and taken up anew on re-assembly. This journal is