160540-47-6Relevant academic research and scientific papers
First Total Synthesis of (+/-)-Oxerine
Aoyagi, Yutaka,Inariyama, Taku,Arai, Yaeko,Tsuchida, Sanae,Matuda, Yasuko,et al.
, p. 13575 - 13582 (1994)
Total synthesis of (+/)-oxerine (1), a monoterpene alkaloid, starting from 3-bromopyridine (7) is described.The key reaction in this sequence is the samarium iodide (SmI2)-mediated intramolecular cyclization of γ-ethynyl bromide (4).
