First Total Synthesis of (+/-)-Oxerine

DOI: 10.1016/S0040-4020(01)85672-6

Source and publish data:

Tetrahedron p. 13575 - 13582 (1994)

Update date:2022-08-05

Topics: Catalyst Stereochemistry Total synthesis Reagent Diastereomers

Authors:

Aoyagi, Yutaka

Inariyama, Taku

Arai, Yaeko

Tsuchida, Sanae

Matuda, Yasuko

et al. et al.

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Article abstract of DOI:10.1016/S0040-4020(01)85672-6

Total synthesis of (+/)-oxerine (1), a monoterpene alkaloid, starting from 3-bromopyridine (7) is described.The key reaction in this sequence is the samarium iodide (SmI2)-mediated intramolecular cyclization of γ-ethynyl bromide (4).

Full text of DOI:10.1016/S0040-4020(01)85672-6

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