1606139-32-5Relevant articles and documents
Silver-catalyzed cross-coupling of propargylic alcohols with isocyanides: An atom-economical synthesis of 2,3-ALLENAMIDES
Liu, Jianquan,Liu, Zhenhua,Wu, Nannan,Liao, Peiqiu,Bi, Xihe
, p. 2154 - 2158 (2014/03/21)
Cross-coupling reactions between propargylic alcohols and isocyanides, by means of silver catalysis, have been described. This new reaction is both atom and step efficient and is applicable to a broad scope of substrates, allowing the synthesis of a range of synthetically valuable 2,3-allenamides in moderate to excellent yields. Making allenamides: Cross-coupling reactions between propargylic alcohols and isocyanides, by means of silver catalysis, are described. This new reaction is both atom and step efficient and is applicable to a broad scope of substrates, allowing the synthesis of a range of synthetically valuable 2,3-allenamides in moderate to excellent yields (see scheme). Copyright