1606160-01-3

Upstream product

• 108-98-5 thiophenol 
• 1606160-00-2 C₂₂H₃₀⁽²⁾HNO₁₄ 
• 6813-81-6 N-acetyl neuraminic acid 

Downstream Products

• 1158806-27-9 methyl 5-acetamido-4,7,8,9-tetra-O-acetyl-2,6-anhydro-3,5-dideoxy-3-²H-D-glycero-D-galacto-non-2-enonate 
• 73960-72-2 methyl-2,3-didehydro-4,7,8,9-tetra-O-acetyl-N-acetylneuraminate 
• 1606160-15-9 methyl [phenyl 4,7,8,9-tetra-O-acetyl-3-(R)-3-2H-3,5-dideoxy-2-thio-5-trifluroacetamido-D-glycero-α-D-galacto-non-2-ulopyranoside]onate 
• 1606160-21-7 methyl [phenyl 7,8,9-tri-O-acetyl-5-amino-5,4-N,O-carbonyl-3-(R)-3-²H-3,5-dideoxy-2-thio-D-glycero-α-D-galacto-non-2-ulopyranoside]onate 

Relevant academic research and scientific papers

Synthesis and elimination of C-3-labeled thiosialosides

The synthesis of C-3-labeled phenylthio sialic acid derivatives and an investigation of stereoselectivity in elimination reactions for the synthesis of 2,3-dehydro derivatives (glycals) is described. The experimental results are consistent with the existence of a conformational change and may be indicative of the intermediacy of an all-axial oxacarbenium ion.