1606160-21-7Relevant articles and documents
Synthesis and elimination of C-3-labeled thiosialosides
De Meo, Cristina,Wallace, Clare E.,Geringer, Scott A.
supporting information, p. 2676 - 2679 (2014/06/09)
The synthesis of C-3-labeled phenylthio sialic acid derivatives and an investigation of stereoselectivity in elimination reactions for the synthesis of 2,3-dehydro derivatives (glycals) is described. The experimental results are consistent with the existence of a conformational change and may be indicative of the intermediacy of an all-axial oxacarbenium ion.