160651-63-8

Upstream product

• 160651-61-6 2-Deoxy-4,5:6,7-di-O-isopropylidene-3-O-methyl-D-gluco-heptose trimethylene dithioacetal 
• 160651-60-5 2-Deoxy-4,5:6,7-di-O-isopropylidene-D-gluco-heptose trimethylene dithioacetal 
• 148324-14-5 2-Deoxy-4,5:6,7-di-O-isopropylidene-D-manno-heptose trimethylene dithioacetal 
• 98-59-9 p-toluenesulfonyl chloride 
• 160651-62-7 2-Deoxy-4,5-O-isopropylidene-3-O-methyl-D-gluco-heptose trimethylene dithioacetal 
• 160651-59-2 2-Deoxy-4,5:6,7-di-O-isopropylidene-3-O-tosyl-D-manno-heptose trimethylene dithioacetal 
• 160651-57-0 Trifluoro-methanesulfonic acid (R)-2-[1,3]dithian-2-yl-1-((4R,5S,4'R)-2,2,2',2'-tetramethyl-[4,4']bi[[1,3]dioxolanyl]-5-yl)-ethyl ester 
• 160651-58-1 2-Deoxy-4,5:6,7-di-O-isopropylidene-3-O-methanesulfonyl-D-manno-heptose trimethylene dithioacetal 

Downstream Products

• 139561-46-9 5a-carba-1,5-anhydro-L-iditol 

Relevant academic research and scientific papers

From sugars to carbocycles. 3. Synthesis of validatol and 4-epi-validatol from mannose and glucose

Validatol (4) and 4-epi-validatol (8) are synthesized from mannose and glucose, respectively. The key step in the synthesis of 4 is the base-induced intramolecular displacement reaction of the epoxy dithiane 14 to yield the six-membered carbocycle 15 excl