Journal of Organic Chemistry p. 6069 - 6074 (1994)
Update date:2022-08-03
Topics:
Krohn
Borner
Gringard
Validatol (4) and 4-epi-validatol (8) are synthesized from mannose and glucose, respectively. The key step in the synthesis of 4 is the base-induced intramolecular displacement reaction of the epoxy dithiane 14 to yield the six-membered carbocycle 15 excl
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Doi:10.1016/j.tetasy.2014.03.001
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