1607-23-4Relevant academic research and scientific papers
Hydrosilylation of Allyl Ethers in the Presence of Platinum(II) Immobilized on Polymethylene Sulfide
Il’ina, M. A.,de Vekki, D. A.
, p. 68 - 77 (2020/04/09)
The reactions of allyl ethyl, allyl butyl, allyl glycidyl, allyl benzyl, and allyl phenyl ethers with 1,1,3,3-tetra-methyldisiloxane in the presence of platinum(II) immobilized on polymethylene sulfide have been studied.
Hydrosilylation of Allyl Ethers in the Presence of Supported Sulfur-Containing Platinum(II) Complexes
de Vekki,Il’ina,Skvortsov
, p. 25 - 35 (2018/03/09)
Hydrosilylation of allyl ethyl, allyl butyl, allyl glycidyl, allyl benzyl, and allyl phenyl ethers by 1,1,3,3-tetramethyldisiloxane in the presence of supported sulfur-containing platinum(II) complexes with the general formula [{SiO2}O2S/
DEHYDROGENATIVE SILYLATION, HYDROSILYLATION AND CROSSLINKING USING PYRIDINEDIIMINE COBALT CARBOXYLATE CATALYSTS
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Page/Page column 55, (2017/02/24)
A process for producing a silylated product comprises reacting a mixture comprising (a) an unsaturated compound containing at least one unsaturated functional group, (b) a silyl hydride containing at least one silylhydride functional group, and (c) a catalyst, optionally in the presence of a solvent, to produce a dehydrogenative silylated product, a hydrosilylated product, or a combination of a dehydrogenative silylated product and a hydrosilylated product, wherein the catalyst is chosen from a pyridine diimine cobalt dicarboxylate complex or a cobalt carboxylate compound, and the process is conducted without pre-activating the catalyst via a reducing agent and/or without an initiator or promoter compound. The present catalysts have been found to be active in the presence of the silyl hydride employed in the silylation reaction.
Hydrosilylation of allyl glycidyl ether with triethoxysilane
Chernyshev,Belyakova,Knyazeva,Khromykh
, p. 55 - 61 (2008/02/13)
Hydrosilylation of allyl glycidyl ether with triethoxysilane in presence of Speier's catalyst leads to triethoxy(3-glycidoxypropyl)silane and triethoxy(2-glycidoxy-1-methylethyl)silane and is accompanied by isomerization of allyl glycidyl ether and cleavage of the oxirane ring and the ether bond. An effect of admixtures in allyl glycidyl ether on the process is revealed. Some other hydrosilylation catalysts and additives to Speier's catalyst are studied.
