1607-23-4Relevant articles and documents
Hydrosilylation of Allyl Ethers in the Presence of Platinum(II) Immobilized on Polymethylene Sulfide
Il’ina, M. A.,de Vekki, D. A.
, p. 68 - 77 (2020/04/09)
The reactions of allyl ethyl, allyl butyl, allyl glycidyl, allyl benzyl, and allyl phenyl ethers with 1,1,3,3-tetra-methyldisiloxane in the presence of platinum(II) immobilized on polymethylene sulfide have been studied.
DEHYDROGENATIVE SILYLATION, HYDROSILYLATION AND CROSSLINKING USING PYRIDINEDIIMINE COBALT CARBOXYLATE CATALYSTS
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Page/Page column 55, (2017/02/24)
A process for producing a silylated product comprises reacting a mixture comprising (a) an unsaturated compound containing at least one unsaturated functional group, (b) a silyl hydride containing at least one silylhydride functional group, and (c) a catalyst, optionally in the presence of a solvent, to produce a dehydrogenative silylated product, a hydrosilylated product, or a combination of a dehydrogenative silylated product and a hydrosilylated product, wherein the catalyst is chosen from a pyridine diimine cobalt dicarboxylate complex or a cobalt carboxylate compound, and the process is conducted without pre-activating the catalyst via a reducing agent and/or without an initiator or promoter compound. The present catalysts have been found to be active in the presence of the silyl hydride employed in the silylation reaction.