160706-88-7Relevant academic research and scientific papers
Complexes of the Platinum Metals. Part 46. 1,1,1,5,5,5-Hexafluoro-3-azapentane-2,4-diiminato Derivatives of Ruthenium, Osmium and Iridium. Crystal Structure of
Hursthouse, Michael B.,Mazid, Muhammed A.,Robinson, Stephen D.,Sahajpal, Arvind
, p. 3615 - 3620 (1994)
Trifluoroacetamidine, NH=C(CF3)-NH2, underwent a condensation reaction in the presence of certain platinum metal hydrides in boiling toluene to liberate ammonia and form complexes containing the N,N'-chelating 1,1,1,5,5,5-hexafluoro-3-azapentane-2,4-diiminate ligand NHC(CF3)NC(CF3)NH.Complexes prepared in this manner were , , (M = Ru or Os) and .Under similar conditions reacted to afford the complex in which intramolecular hydrogen bonding between the non-co-ordinated oxygen of the monodentate trifluoroacetate ligand and the adjacent NH moiety has been detected.An X-ray crystallographic study performed on has confirmed an octahedral ruthenium(II) structure with trans-phosphine ligands and a chelating NHC(CF3)NC(CF3)NH(1-) moiety.
