Journal of the Chemical Society, Dalton Transactions p. 3615 - 3620 (1994)
Update date:2022-08-03
Topics:
Hursthouse, Michael B.
Mazid, Muhammed A.
Robinson, Stephen D.
Sahajpal, Arvind
Trifluoroacetamidine, NH=C(CF3)-NH2, underwent a condensation reaction in the presence of certain platinum metal hydrides in boiling toluene to liberate ammonia and form complexes containing the N,N'-chelating 1,1,1,5,5,5-hexafluoro-3-azapentane-2,4-diiminate ligand NHC(CF3)NC(CF3)NH.Complexes prepared in this manner were a chelating NHC(CF3)NC(CF3)NH(1-) moiety.
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