Complexes of the Platinum Metals. Part 46. 1,1,1,5,5,5-Hexafluoro-3-azapentane-2,4-diiminato Derivatives of Ruthenium, Osmium and Iridium. Crystal Structure of

DOI: 10.1039/DT9940003615

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 3615 - 3620 (1994)

Update date:2022-08-03

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Authors:

Hursthouse, Michael B.

Mazid, Muhammed A.

Robinson, Stephen D.

Sahajpal, Arvind

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Article abstract of DOI:10.1039/DT9940003615

Trifluoroacetamidine, NH=C(CF3)-NH2, underwent a condensation reaction in the presence of certain platinum metal hydrides in boiling toluene to liberate ammonia and form complexes containing the N,N'-chelating 1,1,1,5,5,5-hexafluoro-3-azapentane-2,4-diiminate ligand NHC(CF3)NC(CF3)NH.Complexes prepared in this manner were , , (M = Ru or Os) and .Under similar conditions reacted to afford the complex in which intramolecular hydrogen bonding between the non-co-ordinated oxygen of the monodentate trifluoroacetate ligand and the adjacent NH moiety has been detected.An X-ray crystallographic study performed on has confirmed an octahedral ruthenium(II) structure with trans-phosphine ligands and a chelating NHC(CF3)NC(CF3)NH(1-) moiety.

Full text of DOI:10.1039/DT9940003615

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