1607805-74-2

Upstream product

• 98-88-4 benzoyl chloride 
• 1607805-68-4 ethyl (1S,2S,3R,4S)-2-benzamido-3,4-dihydroxycyclopentanecarboxylate 
• 63838-48-2 6-Azabicyclo<3.2.0>hept-3-en-7-one 
• 1607805-69-5 C₁₅H₁₇NO₅ 
• 1099-45-2 ethyl (triphenylphosphoranylidene)acetate 
• 146864-12-2 (1S,5R)-6-azabicyclo[3.2.0]hept-3-en-7-one 
• 1607805-89-9 ethyl (1S,2R)-2-benzamidocyclopent-3-enecarboxylate 
• 1006611-38-6 C₈H₁₃NO₂ 

Downstream Products

• 1607805-76-4 triethyl (3R,4S)-3-benzamidoheptane-1,4,7-tricarboxylate 

Relevant academic research and scientific papers

A de Novo stereocontrolled approach to syn- and anti-disubstituted acyclic β2,3-amino acid enantiomers

The stereocontrolled syntheses of functionalized acyclic β2,3-amino acid derivatives in enantiomerically pure form were performed by starting from enantiopure cis- and trans-2-aminocyclopent-3- enecarboxylates, which were derived from a racemic bicyclic β-lactam. The synthetic strategy involves the stereoselective dihydroxylaton of the C-C double bond of the cyclopentene β-amino esters. The subsequent NaIO 4-mediated ring cleavage affords dialdehyde intermediates that undergo functionalization by a Wittig reaction. The stereocontrolled syntheses of functionalized acyclic β2,3-amino acid derivatives in enantiomerically pure form have been performed in five steps by starting from enantiopure cis- and trans-2-aminocyclopent-3-enecarboxylates, which were derived from a racemic bicyclic β-lactam. Copyright

A de Novo Stereocontrolled Approach to syn- and anti-Disubstituted Acyclic β2,3-Amino Acid Enantiomers

The stereocontrolled syntheses of functionalized acyclic β2,3-amino acid derivatives in enantiomerically pure form were performed by starting from enantiopure cis- and trans-2-aminocyclopent-3-enecarboxylates, which were derived from a racemic bicyclic β-lactam. The synthetic strategy involves the stereoselective dihydroxylaton of the C-C double bond of the cyclopentene β-amino esters. The subsequent NaIO4-mediated ring cleavage affords dialdehyde intermediates that undergo functionalization by a Wittig reaction.