1607805-88-8

Basic information

• Product Name: ethyl (2S,3S)-3-benzamido-6-oxo-2-(4-oxopentyl)heptanoate
• Synonyms: ethyl (2S,3S)-3-benzamido-6-oxo-2-(4-oxopentyl)heptanoate
• CAS NO: 1607805-88-8
• Molecular Weight: 375.465
• Mol File: 1607805-88-8.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: ethyl (2S,3S)-3-benzamido-6-oxo-2-(4-oxopentyl)heptanoate(CAS DataBase Reference)
• NIST Chemistry Reference: ethyl (2S,3S)-3-benzamido-6-oxo-2-(4-oxopentyl)heptanoate(1607805-88-8)
• EPA Substance Registry System: ethyl (2S,3S)-3-benzamido-6-oxo-2-(4-oxopentyl)heptanoate(1607805-88-8)

Safety Data

• Hazardous Substances Data: 1607805-88-8(Hazardous Substances Data)

Upstream product

• 98-88-4 benzoyl chloride 
• 790657-32-8 C₈H₁₃NO₂ 
• 1607805-66-2 ethyl (1R,2S)-2-benzamidocyclopent-3-enecarboxylate 
• 1607805-67-3 ethyl (1S,2S)-2-benzamidocyclopent-3-enecarboxylate 
• 63838-48-2 6-Azabicyclo<3.2.0>hept-3-en-7-one 
• 138039-48-2 (+)-(1R,2S)-2-aminocyclopent-3-ene-1-carboxylic acid 
• 1607805-78-6 ethyl (1S,2R,3S,4R)-2-benzamido-3,4-dihydroxycyclopentanecarboxylate 
• 1607805-79-7 C₁₅H₁₇NO₅ 
• 1607805-86-6 ethyl (2S,3S,E)-3-benzamido-6-oxo-2-[(E)-4-oxopent-2-enyl]hept-4-enoate 

Relevant articles and documents

A de Novo stereocontrolled approach to syn- and anti-disubstituted acyclic β2,3-amino acid enantiomers

The stereocontrolled syntheses of functionalized acyclic β2,3-amino acid derivatives in enantiomerically pure form were performed by starting from enantiopure cis- and trans-2-aminocyclopent-3- enecarboxylates, which were derived from a racemic bicyclic β-lactam. The synthetic strategy involves the stereoselective dihydroxylaton of the C-C double bond of the cyclopentene β-amino esters. The subsequent NaIO 4-mediated ring cleavage affords dialdehyde intermediates that undergo functionalization by a Wittig reaction. The stereocontrolled syntheses of functionalized acyclic β2,3-amino acid derivatives in enantiomerically pure form have been performed in five steps by starting from enantiopure cis- and trans-2-aminocyclopent-3-enecarboxylates, which were derived from a racemic bicyclic β-lactam. Copyright