160785-39-7Relevant academic research and scientific papers
[1,5]-Brook rearrangement: An overlooked but valuable silyl migration to synthesize configurationally defined vinylsilane. the unique steric and electronic effects of geminal bis(silane)
Gao, Lu,Lu, Ji,Song, Zhenlei,Lin, Xinglong,Xu, Yongjin,Yin, Zhiping
, p. 8961 - 8963 (2013)
An unusual [1,5]-Brook rearrangement of the lithium alkoxide of geminal bis(silyl) homoallylic alcohol is described. The unique steric and electronic effects of geminal bis(silane) were found to be crucial for promoting this long-range silyl migration, as
