[1,5]-Brook rearrangement: An overlooked but valuable silyl migration to synthesize configurationally defined vinylsilane. the unique steric and electronic effects of geminal bis(silane)

DOI: 10.1039/c3cc45002c

Source and publish data:

Chemical Communications p. 8961 - 8963 (2013)

Update date:2022-08-04

Topics:

Authors:

Gao, Lu Gao, Lu

Lu, Ji Lu, Ji

Song, Zhenlei

Lin, Xinglong

Xu, Yongjin

Yin, Zhiping

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Article abstract of DOI:10.1039/c3cc45002c

An unusual [1,5]-Brook rearrangement of the lithium alkoxide of geminal bis(silyl) homoallylic alcohol is described. The unique steric and electronic effects of geminal bis(silane) were found to be crucial for promoting this long-range silyl migration, as

Full text of DOI:10.1039/c3cc45002c

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