1608154-10-4Relevant academic research and scientific papers
A clear-cut example of selective Bpin-Bdan activation and precise Bdan transfer on boron conjugate addition
Cid, Jessica,Carbo, Jorge J.,Fernandez, Elena
, p. 3616 - 3620 (2014)
Activating the non-symmetrical Bpin-Bdan diboron reagent with alkoxide leads to the formation of two possible adducts: MeO-→Bpin-Bdan or MeO-→Bdan-Bpin. Experimental and theoretical investigation confirms that the MeO-→Bpin interaction is preferred and thus selective formation of a C-Bdan bond upon reaction with an activated C=C bond.
