1609376-67-1Relevant academic research and scientific papers
A bowl-shaped molecule for organic field-effect transistors: Crystal engineering and charge transport switching by oxygen doping
Shi, Ke,Lei, Ting,Wang, Xiao-Ye,Wang, Jie-Yu,Pei, Jian
, p. 1041 - 1045 (2014)
A corannulene-based derivative was facilely developed with a bowl-shaped structure. Highly ordered cofacial convex-concave stacking was realized through tuning the molecular dipoles, which is favorable for charge transport. Organic field-effect transistors were fabricated, providing opportunities for a broad class of corannulene derivatives and buckybowl aromatics for application in future organic electronic devices. The Royal Society of Chemistry 2014.
Meso-β Dibenzo[ a,g ]corannulene-fused porphyrins
Ota, Kensuke,Tanaka, Takayuki,Osuka, Atsuhiro
supporting information, p. 2974 - 2977 (2014/06/23)
FeCl3-mediated oxidative fusion of meso-linked dibenzo[a,g]corannulene-porphyrin dyads 6M afforded fused porphyrins 7M bearing a five-membered ring connection, but similar oxidation of β-linked dyads 9M provided fused porphyrins 10M bearing a six-membered ring connection, both in a regiospecific manner. While fused dyads 10M exhibit modestly red-shifted absorption and fluorescence profiles, fused dyads 7M display characteristically red-shifted absorption bands reflecting antiaromatic dehydropurpurin electronic networks.
