1609405-79-9Relevant academic research and scientific papers
Ruthenium-Catalyzed C–H Amidation and Alkenylation of Cyclic N-Sulfonyl Ketimines
Manoharan, Ramasamy,Jeganmohan, Masilamani
, p. 4013 - 4019 (2016)
A highly regioselective ruthenium-catalyzed C–H amidation of cyclic N-sulfonyl ketimines with organic sulfonyl azides is described. An alkenylation at the C–H bond of cyclic N-sulfonyl ketimines with various alkenes was also carried out. Only a catalytic
Aerobic oxidative C-H olefination of cyclic N-sulfonyl ketimines catalyzed by a rhodium catalyst
Wang, Nan-Jin,Mei, Shu-Tao,Shuai, Li,Yuan, Yi,Wei, Ye
supporting information, p. 3040 - 3043 (2014/06/23)
A useful method for the synthesis of ortho-olefinated ketimines from readily accessible cyclic N-sulfonyl ketimines and various olefins has been achieved. The reactions proceeded by Rh(III)-catalyzed, N-sulfonyl ketimine-directed C-H cleavage under aerobic conditions. Further synthetic transformations of the olefinic products led to interesting heterocyclic molecules.
