1609538-14-8Relevant articles and documents
Development of 3,5-Di- tert -butylphenol as a Model Substrate for Biomimetic Aerobic Copper Catalysis
Kwon, Ohhyeon,Esguerra, Kenneth Virgel N.,Glazerman, Michael,Petitjean, Laurène,Xu, Yalun,Ottenwaelder, Xavier,Lumb, Jean-Philip
supporting information, p. 1548 - 1553 (2017/08/11)
We develop 3,5-di- tert butylphenol as a strategic substrate for the evaluation of biomimetic Cu 2 -O 2 complexes intended to mimic the activity of tyrosinase. We describe a practical and scalable synthesis and validate its use in an aerobic ortho -oxygenation catalyzed by N, N ′-di- tert -butylethylenediamine and [Cu(CH 3 CN) 4 ]PF 6.