160983-22-2Relevant articles and documents
Chromium(II)-Mediated Synthesis of 1,1-Bis(trimethylsilyl)alkenes from Aldehydes and (Me3Si)2CBr2
Hodgson, David M.,Comina, Paul J.
, p. 9469 - 9470 (1994)
The synthesis of 1,1-bis(trimethylsilyl)alkenes from aldehydes and (Me3Si)2CBr2 using CrCl2 is described.
Chromium(II)-mediated synthesis of vinylbis(silanes) from aldehydes and a study of acid- and base-induced reactions of the derived epoxybis(silanes): A synthesis of acylsilanes
Hodgson, David M.,Comina, Paul J.,Drew, Michael G. B.
, p. 2279 - 2289 (2007/10/03)
The synthesis of vinylbis(silanes) 1 from aldehydes and dibromomethylenebis(trimethylsilane) using chromium(II) chloride in DMF is described. Epoxidation of vinylbis(silanes) 1 and treatment of the resulting epoxybis(silanes) 2 with sulfuric acid in metha