66270-64-2Relevant academic research and scientific papers
Chromium(II)-mediated synthesis of vinylbis(silanes) from aldehydes and a study of acid- and base-induced reactions of the derived epoxybis(silanes): A synthesis of acylsilanes
Hodgson, David M.,Comina, Paul J.,Drew, Michael G. B.
, p. 2279 - 2289 (2007/10/03)
The synthesis of vinylbis(silanes) 1 from aldehydes and dibromomethylenebis(trimethylsilane) using chromium(II) chloride in DMF is described. Epoxidation of vinylbis(silanes) 1 and treatment of the resulting epoxybis(silanes) 2 with sulfuric acid in metha
Vinyldisilanes as masked acylsilanes
Hodgson, David M.,Comina, Paul J.
, p. 755 - 756 (2007/10/03)
The synthesis of acylsilanes 3 from vinyldisilanes 1 by epoxidation and treatment of the resulting epoxydisilanes 2 with H2SO4 in MeOH is described.
