1610-17-9

Basic information

• Product Name: ATRATON
• Synonyms: 2-ETHYLAMINO-4-ISOPROPYLAMINO-6-METHOXY-1,3,5-TRIAZINE;2-[ETHYLAMINO]-4-[ISOPROPYLAMINO]-6-METHOXY-S-TRIAZINE;2-METHOXYATRAZINE;ATRATON;ATRAZINE-METHOXY;GESATAMIN;1,3,5-Triazine-2,4-diamine, N-ethyl-6-methoxy-N'-(1-methylethyl)-;2-ethylamino-4-isopropylamino-6-methoxy-s-triazin
• CAS NO: 1610-17-9
• Molecular Formula: C₉H₁₇N₅O
• Molecular Weight: 211.26
• EINECS: 216-547-5
• Mol File: 1610-17-9.mol
• Article Data: 5

Chemical Properties

• Boiling Point: 350.95°C (rough estimate)
• Flash Point: 11 °C
• Appearance: /Solid
• Density: 1.161
• Vapor Pressure: 3.9E-05mmHg at 25°C
• Refractive Index: 1.7610 (estimate)
• Storage Temp.: APPROX 4°C
• PKA: 4.31±0.41(Predicted)
• Water Solubility: 1.67g/L(25 oC)
• BRN: 613098
• CAS DataBase Reference: ATRATON(CAS DataBase Reference)
• NIST Chemistry Reference: ATRATON(1610-17-9)
• EPA Substance Registry System: ATRATON(1610-17-9)

Safety Data

• Hazard Codes: Xn,T,F
• Statements: 22-39/23/24/25-23/24/25-11
• Safety Statements: 22-24/25-45-24-16-7
• RIDADR: UN1230 3/PG 2
• WGK Germany: 3
• RTECS: XY8750000
• Hazardous Substances Data: 1610-17-9(Hazardous Substances Data)

Usage

Uses

Atraton is a toxic herbicide and an environmental contaminants.

Definition

ChEBI: A diamino-1,3,5-triazine that is N-ethyl-N'-(propan-2-yl)-1,3,5-triazine-2,4-diamine substituted by a methoxy group at position 6. It is an agrochemical used as a herbicide.

General Description

Atraton is a triazine herbicide intended to control weeds in a variety of crops. Triazines herbicides act by inhibiting photosynthesis in all organisms with oxygen-evolving photosystems.

InChI:InChI=1/C9H17N5O/c1-5-10-7-12-8(11-6(2)3)14-9(13-7)15-4/h6H,5H2,1-4H3,(H2,10,11,12,13,14)

Upstream product

• 67-56-1 methanol 
• 1912-24-9 6-chloro-N-ethyl-N'-isopropyl-1,3,5-triazine-2,4-diamine 

Downstream Products

• 2163-68-0 Hydroxyatrazine 
• 30360-56-6 Desisopropylatraton 

Relevant articles and documents

Atrazine transformation using synthetic enzymes prepared by molecular imprinting.

Atrazine imprinted synthetic polymers were prepared using a combination of methacrylic acid and 2-sulfoethyl methacrylate that bound and converted atrazine and other 6-chlorotriazine herbicides to less toxic compounds. A chloride at the 6-position of the triazines was converted to a methoxy group by the polymer in a methanol-containing solvent, where the imprinting effects enhanced the catalytic activity. Competitive inhibition of the atrazine methanolysis was observed in the presence of a structurally related binder, ametryn, suggesting that the catalytic reaction proceeded in the binding sites generated by the molecular imprinting process.

Atrazine transforming polymer prepared by molecular imprinting with post-imprinting process

Molecularly imprinted polymers bearing atrazine transforming activity were prepared by using newly designed templates that are atrazine analogues attached with an allyl or a styryl group via a disulfide bond at the 6-position, methacrylic acid as a functional monomer and styrene/divinylbenzene as crosslinkers. After polymerization, the disulfide bond was reduced to remove the atrazine moiety from the polymer matrix, followed by oxidation of the remaining thiol group to generate sulfonic acid (post-imprinting treatment), so that both a methacrylic acid residue and a sulfonic acid residue existed in an atrazine-imprinted cavity. The polymers indicated the selective binding of triazine herbicides and catalytic activity for methanolysis at the 6-position of atrazine, yielding a low toxic atraton. The Royal Society of Chemistry.

5,6-Dihydro-1,2,4,6-thiatriazin-5-one-1,1-dioxides

5,6-Dihydro-1,2,4,6-thiatriazin-5-one-1,1-dioxides of the formula STR1 where R1 is hydrogen, a metal atom or an unsubstituted or substituted ammonium radical, R2 is a saturated or unsaturated straight-chain aliphatic radical of up to 10 carbon atoms, a cycloaliphatic radical or 3 to 7 carbon atoms, a branched saturated or unsaturated aliphatic radical of 3 to 10 carbon atoms, a halogen-, alkoxy- or alkylmercapto-substituted aliphatic radical of 2 to 10 carbon atoms tetrahydrofuryl substituted methyl, a cycloalkoxy-substituted aliphatic radical of 4 to 10 carbon atoms, unsubstituted or halogen-substituted benzyl or phenyl, halophenyl, or alkylphenyl of a total of up to 10 carbon atoms, R3 is hydrogen, a straight-chain aliphatic radical of up to 10 carbon atoms, a cycloaliphatic radical of 3 to 7 carbon atoms, a branched aliphatic radical of 3 to 10 carbon atoms, haloalkyl, or alkoxyalkyl of 2 to 10 carbon atoms and X is oxygen and may also be sulfur if R2 is unsubstituted or halogen-substituted benzyl, processes for their preparation, and herbicides containing the above compounds.