1610049-44-9Relevant academic research and scientific papers
Organocatalytic domino reaction of electron-deficient 2,4-dienes with 2-halo-1,3-dicarbonyl compounds: A highly regio-and stereoselective approach to functionalized five-membered carbocycles
Xie, Jian-Wu,Xu, Mei-Lan,Zhang, Ren-Zun,Pan, Jin-Yun,Zhu, Wei-Dong
supporting information, p. 395 - 400 (2014/05/20)
An unexpected domino reaction of electron- deficient 2,4-dienes with 2-halo-1,3-dicarbonyl compounds, employing the readily available N-(4- trifluoromethylbenzyl)cinchonium bromide as the phase-transfer catalyst, provides an access to functionalized cyclopentenes and fulvene derivatives with excellent regio-, chemo- and stereoselectivities. A plausible mechanism for this unprecedented domino reaction is given.
