1610542-23-8

Basic information

• Product Name: diethyl fluoronitromethylphosphonate
• Synonyms: diethyl fluoronitromethylphosphonate
• CAS NO: 1610542-23-8
• Molecular Weight: 215.118
• Mol File: 1610542-23-8.mol

Chemical Properties

• CAS DataBase Reference: diethyl fluoronitromethylphosphonate(CAS DataBase Reference)
• NIST Chemistry Reference: diethyl fluoronitromethylphosphonate(1610542-23-8)
• EPA Substance Registry System: diethyl fluoronitromethylphosphonate(1610542-23-8)

Safety Data

• Hazardous Substances Data: 1610542-23-8(Hazardous Substances Data)

Upstream product

• 53753-37-0 diethyl (nitromethyl)phosphonate 

Downstream Products

• 1610542-27-2 [(Z)-2-fluoro-2-nitroethenyl]benzene 
• 1610542-34-1 (2-fluoro-2-nitrovinyl)benzene 
• 1610542-30-7 1-chloro-4-[(Z)-2-fluoro-2-nitroethenyl]benzene 
• 1610542-37-4 1-(2-fluoro-2-nitrovinyl)-4-chlorobenzene 
• 1610542-31-8 1-[(Z)-2-fluoro-2-nitroethenyl]-4-(methyloxy)benzene 
• 1610542-38-5 1-(2-fluoro-2-nitrovinyl)-4-methoxybenzene 
• 1610542-32-9 1-[(Z)-2-fluoro-2-nitroethenyl]-4-nitrobenzene 
• 1610542-33-0 1,3-dichloro-5-[3-(2-fluoro-2-nitrovinyl)phenoxy]benzene 
• 1610542-39-6 1,3-dichloro-5-[3-(2-fluoro-2-nitrovinyl)phenoxy]benzene 
• 1610542-40-9 (2-fluoro-2-nitro-1-trifluoromethylvinyl)benzene 
• 1610542-45-4 diethyl (1-fluoro-1-nitro-4-oxo-4-phenylbutyl)phosphonate 
• 1610542-48-7 diethyl (1-fluoro-1,3-dinitro-2-phenylpropyl)phosphonate 
• 1610542-51-2 C₉H₉FN₂O₄ 

Relevant articles and documents

Diethyl fluoronitromethylphosphonate: Synthesis and application in nucleophilic fluoroalkyl additions

Diethyl fluoronitromethylphosphonate (3), a previously unknown compound, was synthesized by electrophilic fluorination of diethyl nitromethylphosphonate with Selectfluor. Base-induced decomposition of 3 was studied by NMR spectroscopy, which identified diethyl fluorophosphate and fluoronitromethane as the main decomposition products. C H acidities [pKa values in dimethyl sulfoxide (DMSO)] of 3, 1-fluoro-1-phenylsulfonylmethanephosphonate (1; McCarthy's reagent), tetraethyl fluoromethylenebisphosphonate (2), and some nonfluorinated phosphonates were computed, and a good correlation between calculated and experimental pKa values was found. The calculated C-H acidities increased in the sequence 2a,b-unsaturated carbonyl compounds, sulfones, and nitro compounds allowed access to variously modified diethyl 1-fluoro-1-nitrophosphonates.