1610675-92-7Relevant academic research and scientific papers
Novel benzazaphosphol-3-one 1-oxide derivatives and its synthetic method
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Paragraph 0057 - 0059; 0073 - 0075, (2016/12/01)
The present invention relates to novel benzazaphosphol-3-one 1-oxide derivatives and a manufacturing method thereof. According to the present invention, the manufacturing method of the benzazaphosphol-3-one 1-oxide derivatives selectively synthesizes the benzazaphosphol-3-one 1-oxide derivatives through an oxidative carbon-nitrogen binding reaction of phosphonamide derivatives as a starting material, in the presence of an oxidizing agent and a halogen-based additive. According to the present invention, the benzazaphosphol-3-one 1-oxide derivatives exhibit physiological activities, and can be used in the pharmaceutical industry.COPYRIGHT KIPO 2016
Metal-free azaphosphaannulation of phosphonamides through intramolecular oxidative C-N bond formation
Kim, Yea Rin,Cho, Seungyoon,Lee, Phil Ho
supporting information, p. 3098 - 3101 (2014/06/23)
We report an efficient metal-free azaphosphaannulation of a myriad of phosphonamides through intramolecular oxidative C-N bond formation using PhI(OAc)2 and iodine in acetonitrile under air, thus leading to the formation of benzazaphosphol-3-on
