25539-14-4

Usage

Uses

Used in Heat Transfer Fluids:
3,5-Dimethylphenylphenyl ether is utilized as a heat transfer fluid for its thermal stability and heat capacity, making it suitable for applications requiring efficient temperature regulation in industrial processes.
Used as a Solvent:
In various industries, 3,5-Dimethylphenylphenyl ether serves as a solvent due to its ability to dissolve a wide range of substances, facilitating processes in fields such as manufacturing and chemical engineering.
Used in Pharmaceutical Production:
3,5-Dimethylphenylphenyl ether is used as a chemical intermediate in the production of pharmaceuticals, contributing to the synthesis of various medicinal compounds.
Used in Dye and Perfume Industries:
This ether is employed in the creation of dyes and perfumes, capitalizing on its chemical structure to produce a range of colorants and fragrances.
Used in Polymer Synthesis:
3,5-Dimethylphenylphenyl ether is utilized in the synthesis of polymers, playing a role in the development of new materials with specific properties for various applications.
Used as a Reagent in Organic Chemistry:
In organic chemistry, 3,5-Dimethylphenylphenyl ether is used as a reagent, participating in a variety of chemical reactions to produce desired organic compounds.

InChI:InChI=1/C14H14O/c1-11-8-12(2)10-14(9-11)15-13-6-4-3-5-7-13/h3-10H,1-2H3

Upstream product

• 108-86-1 bromobenzene 
• 108-68-9 3,5-Dimethylphenol 
• 22445-41-6 3,5-dimethylphenyl iodide 
• 108-95-2 phenol 
• 591-50-4 iodobenzene 
• 3240-34-4 [bis(acetoxy)iodo]benzene 
• 98-80-6 phenylboronic acid 
• 603-33-8 triphenylbismuthane 
• 98-95-3 nitrobenzene 
• 172975-69-8 3,5-dimethylphenyl boronic acid 
• 108-90-7 chlorobenzene 
• 556-96-7 5-bromo-1,3-xylene 

Downstream Products

• 1610675-72-3 ethyl 2,6-dimethyl-4-phenoxyphenylphosphonamide 
• 1610675-92-7 5-phenoxy-7-methyl-1,2-dihydro-1-ethoxy-3H-2,1-benzazaphosphol-3-one 1-oxide 

Relevant academic research and scientific papers

Enhanced catalytic properties of copper in O- and N-arylation and vinylation reactions, using phosphorus dendrimers as ligands

Imino pyridine-capped phosphorus dendrimers were found to strongly enhance the catalytic activity of copper in arylations and vinylations of O- and N-nucleophiles. These reactions could indeed be performed under very mild conditions, often the mildest to

Effect of water in fabricating copper nanoparticles onto reduced graphene oxide nanosheets: Application in catalytic ullmann-coupling reactions

Copper nanoparticles fabricated onto reduced graphene oxide (Cu NPs/rGO) were successfully synthesized via a one-pot dimethylformamide (DMF) reduction approach with an addition of nominal water. This small amount of water can significantly decrease the de

Ligand- and Counterion-Assisted Phenol O-Arylation with TMP-Iodonium(III) Acetates

High reactivity of trimethoxyphenyl (TMP)-iodonium(III) acetate for phenol O-arylation was achieved. It was first determined that the TMP ligand and acetate anion cooperatively enhance the electrophilic reactivity toward phenol oxygen atoms. The proposed method provides access to various diaryl ethers in significantly higher yields than the previously reported techniques. Various functional groups, including aliphatic alcohol, boronic ester, and sterically hindered groups, were tolerated during O-arylation, verifying the applicability of this ligand- and counterion-assisted strategy.

Fabrication of Metal Nanoparticle Composites by Slow Chemical Reduction of Metal-Organic Frameworks

Constructing metal nanoparticle (MNP) composites from metal-organic framework (MOF) precursors has attracted extensive attention as the MOF precursors provide an excellent porous matrix for the generation of MNP composites, which enables the direct fabric

Ligand compound for copper catalyzed aryl halide coupling reaction, catalytic system and coupling reaction

The invention provides a ligand compound capable of being used for copper catalyzed aryl halide coupling reaction, the ligand compound is a three-class compound containing a 2-(substituted or non-substituted) aminopyridine nitrogen-oxygen group, and the invention also provides a catalytic system for the aryl halide coupling reaction. Thecatalytic system comprises a copper catalyst, a compound containing a 2-(substituted or non-substituted) aminopyridine nitrogen-oxygen group adopted as a ligand, alkali and a solvent, and meanwhile, the invention also provides a system for the aryl halide coupling reaction adopting the catalyst system. The compound containing the 2-(substituted or non-substituted) aminopyridine nitrogen oxygen group can be used as the ligand for the copper catalyzed aryl chloride coupling reaction, and the ligand is stable under a strong alkaline condition and can well maintain catalytic activity when being used for the copper-catalyzed aryl chloride coupling reaction. In addition, the copper catalyst adopting the compound as the ligand can particularly effectively promote coupling of copper catalyzed aryl chloride and various nucleophilic reagents which are difficult to generate under conventional conditions, C-N, C-O and C-S bonds are generated, and numerous useful small molecule compounds are synthesized. Therefore, the aryl halide coupling reaction has a very good large-scale application prospect by adopting the copper catalysis system of the ligand.

Solvent-free palladium-catalyzed C–O cross-coupling of aryl bromides with phenols

A new solvent-free procedure for C–O cross-coupling between phenols and aryl bromides comprising of Pd2(dba)3/ButBrettPhos catalytic system is efficient for substrates bearing donor or acceptor, as well as bulky substituents.

CoII Immobilized on Aminated Magnetic-Based Metal–Organic Framework: An Efficient Heterogeneous Nanostructured Catalyst for the C–O Cross-Coupling Reaction in Solvent-Free Conditions

Abstract: In this paper, we report the synthesis of Fe3O4?AMCA-MIL53(Al)-NH2-CoII NPs based on the metal–organic framework structures as a magnetically separable and environmentally friendly heterogeneous nanocatalyst. The prepared nanostructured catalyst efficiently promotes the C–O cross-coupling reaction in solvent-free conditions without the need for using toxic solvents and/or expensive palladium catalyst. Graphic Abstract: [Figure not available: see fulltext.].

Design of BNPs-TAPC Palladium Complex as a Reusable Heterogeneous Nanocatalyst for the O-Arylation of Phenols and N-Arylation of Amines

The thermally stable new heterogenous nanocatalyst BNPs@SiO2(CH2)3-TAPC-O-CH2CH2NH2-Pd(0) was synthesized, characterized and successfully applied in carbon-heteroatom (C–O and C–N) coupling reactions of aryl halides with phenols and amines. The formation of resultant nanocatalyst was approved by FT-IR, XRD, TGA, XPS and EDX techniques. The morphology of BNPs@SiO2(CH2)3-TAPC-O-CH2CH2NH2-Pd(0) was characterized using scanning and transmission electron microscopes. The leaching of palladium from the surface of the catalyst was studid by ICP-OES technique. Noteworthy, the highly active BNPs@SiO2(CH2)3-TAPC-O-CH2CH2NH2-Pd(0) can be easily recycled and reused for six times with negligible loss in its activity. Some remarkable advantages of this method are the shorter reaction times, milder conditions, no needs for an inert atmosphere, high yields and easy separation. Graphical Abstract: [Figure not available: see fulltext.].

Fe3O4@SiO2-copper sucrose xanthate as a green nanocatalyst for N-, O- and S-arylation

Formation of C(sp2)–X bonds was carried out using a Fe3O4@SiO2-copper(I) sucrose xanthate nanoparticle catalyst with the aid of the copper(I) xanthate moiety in the catalyst which was prepared from the reaction between sucrose and carbon disulfide through an alkaline medium via the traditional Zeise approach. Various techniques were employed for the characterization of these novel nanoparticles. Three sorts of heteroatoms, N, O and S, successfully underwent heteroatom arylation to produce secondary or tertiary amines, ethers and thioethers, respectively.

Copper(I)-USY as a Ligand-Free and Recyclable Catalyst for Ullmann-Type O-, N-, S-, and C-Arylation Reactions: Scope and Application to Total Synthesis

The copper(I)-doped zeolite CuI-USY proved to be a versatile, efficient, and recyclable catalyst for various Ullmann-type coupling reactions. Easy to prepare and cheap, this catalytic material enables the arylation and heteroarylation of diverse O-, N-, S-, and C-nucleophiles under ligand-free conditions while exhibiting large functional group compatibility. The facility of this catalyst to promote C-O bond formation was further demonstrated with the total synthesis of 3-methylobovatol, a naturally occurring diaryl ether of biological relevance. From a mechanistic viewpoint, two competitive pathways depending on the nature of the nucleophile and consistent with the obtained results have been proposed.