161194-40-7Relevant articles and documents
Gas Chromatography/Electron Impact Mass Spectrometry Applied to the Differentiation of the Positional Isomers of Long-chain n-Alkylcyclohexanones
Rontani, J.-F.,Giusti, G.
, p. 773 - 776 (1989)
The influence of n-butyl group position upon the fragmentation behaviour of the three isomeric n-butylcyclohexanones was studied.The different fragmentation processes are described and have been applied to the differentation of the positional isomers of long-chain n-alkylcyclohexanones.In the case of the 4-n-alkyl isomers, an interesting mechanism involving a recyclization is proposed and substantiated by deuterium labelling.